Spectroscopy — Synthesis and Characterization of Schiff Base Polymers via Metal Coordination and Its Application in Infrared Stealth Coating

4 measurement groups · 18 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

D230-PyAL-Cu coating · Thin Film

FTIR/XPS used to evaluate coordination; ICP determined Cu content; UV-Vis used to determine optical band gap

Context: Cu-coordinated polymer coating
Measurement source: 4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR imine bond after coordination	1646 cm^-1	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2a
optical band gap	3.40 eV	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Cu2+ coordination content by ICPMarked as a best value within this paper	almost 3.8%	0.038 fraction	—	Text Approximate	5 · 3.1. Synthesis of Polymers and Coordination Polymers
UV-Vis onset absorption	365 nm	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Cu 2p3/2 binding energy after coordination	931.9 eV	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2d

D230-PyAL coating/polymer · Thin Film

1H NMR in CDCl3 at 300 K; UV-Vis used to determine optical band gap; FTIR/XPS used for structure assignment

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR imine bond stretching vibration	1647 cm^-1	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2a
optical band gap	3.45 eV	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
UV-Vis onset absorption	359 nm	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1

D230-PyAL-Ni coating · Thin Film

FTIR/XPS used to evaluate coordination; ICP determined Ni content; UV-Vis used to determine optical band gap

Context: Ni-coordinated polymer coating
Measurement source: 4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR imine bond after coordination	1652 cm^-1	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2a
optical band gap	3.32 eV	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Ni2+ coordination content by ICP	at least 1.2%	0.012 fraction	—	Text Approximate	5 · 3.1. Synthesis of Polymers and Coordination Polymers
UV-Vis onset absorption	374 nm	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Ni 2p3/2 binding energy after coordination	854.7 eV	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2c

D230-PyAL-Sm coating · Thin Film

FTIR/XPS used to evaluate coordination; ICP determined Sm content; UV-Vis used to determine optical band gap

Context: Sm-coordinated polymer coating
Measurement source: 6 · 3.2. UV-Vis Absorption Spectroscopic Analysis · Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR imine bond after coordination	1645 cm^-1	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2a
optical band gapMarked as a best value within this paper	2.99 eV	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Sm3+ coordination content by ICP	almost 3.6%	0.036 fraction	—	Text Approximate	5 · 3.1. Synthesis of Polymers and Coordination Polymers
UV-Vis onset absorptionMarked as a best value within this paper	414 nm	—	—	Table Exact Reported	6 · 3.2. UV-Vis Absorption · Table 1
Sm 3d5/2 binding energy after coordination	1082.2 eV	—	—	Text Exact Reported	4 · 3.1. Synthesis of Polymers and Coordination Polymers · Figure 2e