Spectroscopy — 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin Valves

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HHTP)2 thin film on quartz glass · Thin Film

100 nm Cu3(HHTP)2 thin film; HOMO and LUMO estimated from UPS and optical bandgap.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical bandgap	Eg = 0.58 eV	—	—	Text Exact Reported	S19 · Section 11 · Figure S21
Co work function	-4.9 eV	—	—	Text Exact Reported	1121 · Results and Discussion · Figure S20
HOMO level	-5.32 eV	—	—	Text Exact Reported	S19 · Section 11 · Figure S21
LSMO work function	-4.8 eV	—	—	Text Exact Reported	1121 · Results and Discussion · Figure S20
LUMO level	-4.74 eV	—	—	Text Exact Reported	S19 · Section 11 · Figure S21

Cu3(HHTP)2 thin film on quartz glass · Thin Film

Cu3(HHTP)2 films with different layer-by-layer growth cycle numbers on quartz glass.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
ligand-to-metal charge-transfer absorbance band	648 nm	—	—	Text Exact Reported	1119 · Results and Discussion · Figure 2b
*pi-pi absorbance band**	363 nm	—	—	Text Exact Reported	1119 · Results and Discussion · Figure 2b
film growth rate	about 5 nm per cycle	—	—	Text Approximate	1119 · Results and Discussion · Figure 2c; Figure S2

100 nm Cu3(HHTP)2 thin film on LSMO/STO · Thin Film

Cu3(HHTP)2 film survey and high-resolution Cu 2p3/2 spectra; C 1s charge reference.

Geometry: thin film
Context: pristine MOF film composition and valence
Measurement source: S11 · Section 5. X-ray Photoelectron Spectroscopy (XPS) Measurements · Figure S9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu 2p3/2 Cu(I) component	932.9 eV	—	—	Text Exact Reported	S11 · Section 5 · Figure S9
Cu 2p3/2 Cu(II) component	934.8 eV	—	—	Text Exact Reported	S11 · Section 5 · Figure S9