UPS and photoelectron-yield measurements used for frontier-level estimates.
Every source method stays verbatim. Subtypes retain distinctions such as ATR versus transmission IR, powder versus single-crystal diffraction, and two- versus four-contact transport.
The same technique may serve transport, electrochemistry, sensing or another scientific purpose.
Filter source method wording, sample context and scientific purpose.
65 measurements
2026 · Activating a Metallization Switch for Record Hydrogen Evolution in Single-Atom Modified Polar MOF Piezocatalysts
Ni SAs@UiO-66-NH2(Hf) powder · Powder · Electronic-state, work-function, valence-band and bandgap comparison of UiO-66, UiO-66-NH2 and Ni SAs@UiO-66-NH2.
2026 · Tailoring Li-ion Storage and Transport in Two-Dimensional Conjugated Metal-Organic Frameworks via Precise Nitrogen Incorporation
Cu-N2-OHBA bulk powder crystals · Powder
2026 · Tailoring Li-ion Storage and Transport in Two-Dimensional Conjugated Metal-Organic Frameworks via Precise Nitrogen Incorporation
Cu-N4-OHBA bulk powder crystals · Powder
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-201 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-202 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
2025 · 2D Rhodium-Isocyanide Frameworks
as-prepared SJTU-203 powder · Powder · stacked and monolayer SJTUs; Table S3 summarises electronic and optical properties
2025 · A Low-Symmetry Copper Benzenehexathiol Coordination Polymer with In-Plane Electrical Anisotropy
Cu5BHT crystal domains · Single Crystal · UPS acquired at 300 K; UV/vis on Cu5BHT deposited on a quartz substrate at room temperature.
2025 · An optoelectronic synapse based on Cu-BHT MOF for multi-wavelength optical logic gates and neuromorphic vision system
Cu-BHT thin film on ultra-white glass substrate · Thin Film · Band gap from absorption truncation; work function from secondary electron cutoff; valence-band edge from UPS.
2025 · Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF Crystals
F2HHTP molecular crystal/model · Model · Calculated HOMO values shown in Figure 2b; ligand UPS in Figure S19 validates downshift with fluorination.
2025 · Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF Crystals
Cu3F2HHTP2 blue powder/rod crystals · Powder · DRS samples: 0.5-1 wt% MOF in barium sulfate; UPS with He I source under ultrahigh vacuum.
2025 · Dirac-cone induced metallic conductivity in Cu3(HHTP)2: high-quality MOF thin films fabricated via ML-driven robotic synthesis
Optimised Cu3(HHTP)2 SURMOF thin film · Thin Film · Scienta R4000 analyser, pass energy 2 eV, 295 K; sample/analyser and lamp angles ca. 90 deg and 45 deg
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-S-HHS solvothermal powder · Powder · Powder pressed on foam copper; He lamp hnu=21.22 eV; Au Fermi-edge correction; IE from cutoff and VBM.
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Se-HHS solvothermal powder · Powder · Powder pressed on foam copper; He lamp hnu=21.22 eV; Au Fermi-edge correction; IE from cutoff and VBM.
2025 · Enhanced Electrical Conductivity by the Heavy Chalcogen Effect in Metal-Organic Frameworks
Cu-Te-HHS solvothermal powder · Powder · Powder pressed on foam copper; He lamp hnu=21.22 eV; Au Fermi-edge correction; IE from cutoff and VBM.
2025 · From Rigid to Flexible: Ce-BTC-MOF-Enabled Self-Powered Photodetectors with Record-High Responsivity and Detectivity
Optimised 320 nm Ce-BTC thin film · Thin Film · UPS of Ce-BTC film used to calculate work function and band positions.
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Cu-HATC powders · Powder · UPS spectra with zoomed low-binding-energy edge
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Cu-HHTC powders · Powder · UPS spectra with zoomed low-binding-energy edge
2025 · Nanoporous synthetic metal: A nickel MOF with an amino-functionalized macrocyclic ligand
Ni-HATC thin film on glass · Thin Film · UPS low-binding-energy edge near Fermi level
2025 · Proton-electron coupling and mixed conductivity in a hydrogen-bonded coordination polymer
Ni-BAND thin film · Thin Film · Electronic characterisation to evaluate n-type doping and shallow-donor behaviour.
2025 · Tuning the dxy Orbital Energy Level in 2D Cobalt-Organic-Framework via in-Plane Conjugated Phthalocyanine for Self-Powered Sensing
2D MOF@Pc nanosheets · Nanosheet · Chemical/electronic structure comparison between 2D MOF and 2D MOF@Pc.
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Cu black powder · Powder · Thermo Scientific Nexsa XPS with He I/He II UPS; -10 V bias for secondary electron cut-off; Au Fermi calibration.
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Ni black powder · Powder · Thermo Scientific Nexsa XPS with He I/He II UPS; -10 V bias for secondary electron cut-off; Au Fermi calibration.
2025 · Tuning the Structure-Property Relationships of Metallophthalocyanine-Based Two-Dimensional Conductive Metal-Organic Frameworks with Different Metal Linkages
CuPc-O-Zn black powder · Powder · Thermo Scientific Nexsa XPS with He I/He II UPS; -10 V bias for secondary electron cut-off; Au Fermi calibration.
2025 · Unveiling high-mobility hot carriers in a two-dimensional conjugated coordination polymer
Cu3BHT film transferred onto highly doped conductive silicon · Thin Film · UV-Vis Cary 5000 and FT-IR Tensor II ATR; UPS with He I 21.11 eV source and negative 9 V substrate bias.
2025 · Volatolomics in Fritillarias and Their Identification by Orientation Controlled cMOF Thin Film Chemiresistors
FCB-related volatolomics adsorbed Cu-HHTP[001] film · Thin Film · UPS of Cu-HHTP[001] before and after adsorption of FCB-related volatolomics.
2024 · 2D Conductive Metal-Organic Frameworks Based on Tetraoxa[8]circulenes as Promising Cathode for Aqueous Zinc Ion Batteries
Cu-TOC black powder / pressed pellet · Powder · Work function from secondary electron cut-off region; HOMO onset from valence band region.
2024 · 2D Conductive Metal-Organic Frameworks Based on Tetraoxa[8]circulenes as Promising Cathode for Aqueous Zinc Ion Batteries
Mn-TOC black powder / pressed pellet · Powder · Work function from secondary electron cut-off region; HOMO onset from valence band region.
2024 · 2D Conductive Metal-Organic Frameworks Based on Tetraoxa[8]circulenes as Promising Cathode for Aqueous Zinc Ion Batteries
Zn-TOC black powder / pressed pellet · Powder · Work function from secondary electron cut-off region; HOMO onset from valence band region.
2024 · MOF-enabled high-density 2D molecular crystal optoelectronic memory transistor with floating gate architecture
Pristine 2D Cu3(HHTP)2 MOF thin film · Thin Film · Energy levels calculated from UPS spectrum and optical band gap for 12 nm-thick Cu3(HHTP)2 film.
2024 · NiCo-MOFs in situ anchored on graphdiyne with metal-like properties form a strongly coupled electron transport interface and construct an ohmic contact to achieve efficient charge-hole spatial separation
NCCG-15 · Powder · full XPS/fine spectra of CG, NC, and NCCG-15; UPS spectra for CG and NC
2024 · Photocatalytic Hydrogen Peroxide Production through Functionalized Semiconductive Metal-Organic Frameworks
EFB-MOF powder · Powder · EVB calculated by subtracting ESECO and EHOMO from 21.2 eV excitation energy.
2024 · Synthesis and structure of a non-van-der-Waals two-dimensional coordination polymer with superconductivity
Cu3BHT micro-crystal array / multicrystalline film · Thin Film · Kratos AXIS Ultra under 3 x 10^-9 Torr; He I UPS at 21.11 eV and monochromatic Al Kalpha XPS at 1486.6 eV; binding energies calibrated to C1s 284.8 eV.
2024 · Three-type precursors for low-temperature solution-processed void-and-crack-free copper(I) iodide films: comparison of electrical conductivities and optical transparency
CuI(1A2P) film on glass · Thin Film · Prepared CuI thin film; PYS measured using Riken Keiki AC-3.
2023 · A Conductive 2D Conjugated Tetrathia[8]circulene-Based Nickel Metal–Organic Framework for Energy Storage
as-synthesised Ni-TTC black powder · Powder · SECO and HOMO/valence-band regions
2023 · Regulating Crystallization and Lead Leakage of Perovskite Solar Cell Via Novel Polyoxometalate-Based Metal–Organic Framework
POMOF-functionalised perovskite film · Thin Film · Control and POMOF-functionalised perovskite films compared for optical band gap, cutoff/onset energies, and calculated valence-band levels.
2023 · Semiconducting Conjugated Coordination Polymer with High Charge Mobility Enabled by “4 + 2” Phenyl Ligands
as-synthesised Cu4DHTTB crystals/powder · Powder · Kratos AXIS Ultra DLD with He I 21.22 eV source; sample biased at 9.0 V; UPS result acquired at 300 K.
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcCu-Cu-30C MOF film · Thin Film · PcCu-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcH2-Cu-30C MOF film · Thin Film · PcH2-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcNi-Cu-30C MOF film · Thin Film · PcNi-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.
2023 · Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves
PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film · Electronic structure of PcM-Cu films; UPS acquired at 300 K in SI.
2023 · Two-Dimensional Conjugated Metal-Organic Frameworks with Large Pore Apertures and High Surface Areas for NO2 Selective Chemiresistive Sensing
HIOTP-Ni black powder · Powder · UV-Vis-NIR from 250 to 2000 nm; UPS used to derive HOMO and LUMO values.
2022 · 2D Metal–Organic Framework Cu3(HHTT)2 Films for Broadband Photodetectors from Ultraviolet to Mid-Infrared
Optimised 12-cycle Cu3(HHTT)2 film on SiO2/Si · Thin Film · UPS secondary cut-off and valence-band regions of Cu3(HHTT)2 film on ITO substrate.
2022 · A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers
DDA-Cu MOF film · Thin Film · experimental HOMO/LUMO, electrical gap, optical gap and exciton binding energy
2022 · Boosting the Optoelectronic Performance by Regulating Exciton Behaviors in a Porous Semiconductive Metal-Organic Framework
RhB+@TbTATAB guest-loaded crystals · Powder · Thermo Scientific Escalab 250Xi, He I hv = 21.2 eV; HOMO from Ecutoff and Eonset, LUMO from HOMO and Eg.
2022 · Li-TFSI endohedral Metal-Organic frameworks in stable perovskite solar cells for Anti-Deliquescent and restricting ion migration
Li-TFSI@NH2-MIL-101 doped HTL film, 20 mg mL-1 · Thin Film · HTL valence-band alignment in devices
2022 · Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks
Ni3(HATI_C1)2 film on heavily doped n-type Si · Thin Film · He I discharge lamp source 21.22 eV, ultrahigh vacuum; films on heavily doped n-type Si transferred air-free.
2022 · Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks
Ni3(HATI_C3)2 film on heavily doped n-type Si · Thin Film · He I discharge lamp source 21.22 eV, ultrahigh vacuum; films on heavily doped n-type Si transferred air-free.
2022 · Precise tuning of interlayer electronic coupling in layered conductive metal-organic frameworks
Ni3(HATI_C4)2 film on heavily doped n-type Si · Thin Film · He I discharge lamp source 21.22 eV, ultrahigh vacuum; films on heavily doped n-type Si transferred air-free.
2022 · sp-Carbon Incorporated Conductive Metal-Organic Framework as Photocathode for Photoelectrochemical Hydrogen Generation
as-synthesised Cu3HHAE2 powder/hexagonal rods · Powder · He I source 21.22 eV under ultrahigh vacuum; SECO and low binding-energy HOMO regions analysed.
2022 · Stacked conductive metal–organic framework nanorods for high-performance vacuum electronic devices
Cu-CAT rough nanorods · Unknown · UPS spectra around secondary electron cut-off and valence band region of Cu-CAT nanorods with corrected bias.
2022 · Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol
Co-TCPP-Ac NS thin film-based sensor · Electrode · Mechanistic spectroscopy on Co-TCPP-Ac NS sensor before and after adsorbing methanol molecules.
2022 · Ultrathin Self-Assembly Two-Dimensional Metal-Organic Framework Films as Hole Transport Layers in Ideal-Bandgap Perovskite Solar Cells
FA0.83Cs0.17Sn0.35Pb0.65I2.9Br0.1 perovskite on Cu3(HHTT)2 · Thin Film · Chemical interaction and energy-level measurements for Cu3(HHTT)2/perovskite and control films.
2021 · Layer-by-layer assembled dual-ligand conductive MOF nano-films with modulated chemiresistive sensitivity and selectivity
x mol% HITP doped Cu-HHTP-10C nanofilm series · Thin Film · UPS measured for Cu-HHTP-10C and HITP-doped films; band alignments show Fermi-level up-shift with HITP dopants.
2020 · 2D Semiconducting Metal–Organic Framework Thin Films for Organic Spin Valves
Cu3(HHTP)2 thin film on quartz glass · Thin Film · 100 nm Cu3(HHTP)2 thin film; HOMO and LUMO estimated from UPS and optical bandgap.
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-btt powder · Powder · Work functions and densities of valence electronic states measured for purified OMCPs.
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-btt powder · Powder · Thermo Scientific Theta-Probe spectrometer, He I = 21.22 eV; work functions/densities of valence states.
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-diett powder · Powder · Thermo Scientific Theta-Probe spectrometer, He I = 21.22 eV; work functions/densities of valence states.
2020 · Controlling the Thermoelectric Properties of Organometallic Coordination Polymers via Ligand Design
purified Ni-ett powder · Powder · Thermo Scientific Theta-Probe spectrometer, He I = 21.22 eV; work functions/densities of valence states.
2020 · Nanorods of a novel highly conductive 2D metal-organic framework based on perthiolated coronene for thermoelectric conversion
Ni-PTC pressed pellet for UPS · Pellet · AXIS Ultra-DLD UHV photoemission system; He I source 21.11 eV; pressed pellet thickness about 0.1 mm.
2020 · Ultrafast in Situ Synthesis of Large-Area Conductive Metal-Organic Frameworks on Substrates for Flexible Chemiresistive Sensing
Cu-BHT-2 min chemiresistor sensor on Si/SiO2/Au interdigitated electrodes · Electrode · Cu-BHT-2min film before and after NH3 exposure
2020 · Unique Thermoelectric Properties Induced by Intrinsic Nanostructuring in a Polycrystalline Thin-Film Two-Dimensional Metal–Organic Framework, Copper Benzenehexathiol
synthesised Cu-BHT film · Thin Film · He-I source at 21.2 eV; analysed using CasaXPS.
2018 · Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver-Sulfur Networks
free-standing Ag-BHT film · Thin Film · UPS of Ag-BHT film acquired at 300 K; Figure 5 compares pristine and reduced Ag-BHT.
2018 · Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illumination
Bulk Ni3(HITP)2 black powder · Powder · UPS valence-band analysis; Fermi level calibrated by Au.
2017 · Layer-by-Layer Assembled Conductive Metal–Organic Framework Nanofilms for Room-Temperature Chemiresistive Sensing
NH3-exposed Cu3(HHTP)2 · Thin Film · FTIR compares Cu3(HHTP)2 and Cu3(HHTP)2-NH3; UPS compares Cu3(HHTP)2-10C and Cu3(HHTP)2-10C-NH3.
2015 · A two-dimensional π-d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour
General Cu-BHT thin-film samples · Thin Film · AXIS Ultra-DLD ultrahigh vacuum photoemission spectroscopy; Al Kalpha 1486.6 eV for XPS; He I 21.11 eV for UPS; base pressure better than 3 x 10^-9 Torr; UPS substrate bias 9 V; films on highly doped conductive silicon.
No mapped measurement matches these filters.
These are the exact source-preserving method strings consolidated by this technique group.
| Raw method label | Mapped measurements |
|---|---|
| Ultraviolet photoelectron spectroscopy (UPS) | 12 |
| ultraviolet photoelectron spectroscopy | 8 |
| Ultraviolet photoelectron spectroscopy | 5 |
| UV-vis absorption, UPS, and derived LUMO calculations | 4 |
| VASP/PBE/PAW DFT band-structure calculations plus UV-vis/UPS/CV measurements | 3 |
| UPS | 3 |
| ultraviolet photoelectron spectroscopy (UPS) | 2 |
| UV-vis-NIR spectroscopy, Tauc plot and UPS | 2 |
| XPS and UPS | 1 |
| UPS, LEIPS and infrared diffuse reflection | 1 |
| UPS energy-level analysis | 1 |
| Ultraviolet photoelectron spectroscopy (UPS) and calculated band alignments | 1 |
| DFT frontier-orbital calculation and ligand UPS | 1 |
| Diffuse reflectance spectroscopy and UPS | 1 |
| UPS and XPS | 1 |
| FTIR and ultraviolet photoelectron spectroscopy after NH3 exposure/adsorption. | 1 |
| UPS and UV-vis-NIR optical bandgap analysis | 1 |
| UPS before/after NH3 sensing | 1 |
| FTIR, EELS, solid-state 13C CP/MAS NMR, XPS, Co K-edge XANES/EXAFS, wavelet transform, UV-vis, UPS | 1 |
| Ultraviolet photoelectron spectroscopy (UPS; Thermo Scientific Escalab 250Xi) | 1 |
| UV-Vis/IR optical absorption and UPS | 1 |
| FTIR, XPS and UPS | 1 |
| UPS and UV-vis diffuse reflectance spectroscopy with Tauc analysis | 1 |
| UV-Vis-NIR spectroscopy, Tauc plot, and ultraviolet photoelectron spectroscopy | 1 |
| He I ultraviolet photoelectron spectroscopy | 1 |
| UV-vis absorption/Tauc analysis and ultraviolet photoelectron spectroscopy (UPS) | 1 |
| Tauc plot from UV-Vis-NIR and photoelectron yield spectroscopy (PYS) | 1 |
| UV-Vis Tauc plot, ultraviolet photoelectron spectroscopy (UPS), and temperature-dependent four-point-probe conductivity | 1 |
| UPS and in situ FTIR before/after methanol adsorption | 1 |
| UV-visible truncation method and UPS with He I source | 1 |
| UPS and UV-vis absorption | 1 |
| UPS and UV/vis absorption spectroscopy | 1 |
| XPS, in situ XPS, and UPS | 1 |
| Ultraviolet photoelectron spectroscopy with He-I 21.2 eV lamp | 1 |