Spectroscopy — NiCo-MOFs in situ anchored on graphdiyne with metal-like properties form a strongly coupled electron transport interface and construct an ohmic contact to achieve efficient charge-hole spatial separation

8 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Raman spectroscopy

Cu-GDY (CG) · Powder

Raman bands for CG

Context: CG component
Measurement source: 3 · XRD and Raman analysis · Fig. 2d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CG Raman D band	1304.78 cm-1	—	—	Text Exact Reported	3 · XRD and Raman analysis · Fig. 2d
CG diacetylene Raman band	1956.97 cm-1	—	—	Text Exact Reported	3 · XRD and Raman analysis · Fig. 2d
CG Raman G band	1510.72 cm-1	—	—	Text Exact Reported	3 · XRD and Raman analysis · Fig. 2d

TRPL fluorescence lifetime

Photoluminescence and fluorescence spectroscopy

Cu-GDY (CG) · Powder

excitation wavelength 542 nm

Context: CG component
Measurement source: 7 · Fluorescence analysis · Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CG average fluorescence lifetime	0.472 ns	—	—	Table Exact Reported	7 · Fluorescence analysis · Table 2

TRPL fluorescence lifetime

Photoluminescence and fluorescence spectroscopy

EY photosensitizer comparison · Unknown

excitation wavelength 542 nm

Context: photosensitizer comparison
Measurement source: 7 · Fluorescence analysis · Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
EY average fluorescence lifetime	0.539 ns	—	—	Table Exact Reported	7 · Fluorescence analysis · Table 2

TRPL fluorescence lifetime

Photoluminescence and fluorescence spectroscopy

pure NiCo-MOF (NC) · Powder

excitation wavelength 542 nm

Context: pristine MOF control
Measurement source: 7 · Fluorescence analysis · Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NC average fluorescence lifetime	0.464 ns	—	—	Table Exact Reported	7 · Fluorescence analysis · Table 2

TRPL fluorescence lifetime

Photoluminescence and fluorescence spectroscopy

NCCG-15 · Powder

excitation wavelength 542 nm

Context: target composite
Measurement source: 7 · Fluorescence analysis · Table 2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NCCG-15 electron migration rate ketMarked as a best value within this paper	0.338 ns-1 in Table 2; text states 0.336 ns-1	—	text/table discrepancy: 0.336 vs 0.338 ns-1	Table Exact Reported	7 · Fluorescence analysis · Table 2
NCCG-15 average fluorescence lifetimeMarked as a best value within this paper	0.456 ns	—	—	Table Exact Reported	7 · Fluorescence analysis · Table 2

UV-vis diffuse reflectance spectroscopy

UV-visible and optical absorption spectroscopy

Cu-GDY (CG) · Powder

BaSO4 reference background; indirect band gap from transformed UV-vis data

Context: CG component
Measurement source: 8 · UV-vis spectroscopy analysis · Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CG indirect band gap	0.35 eV	—	—	Text Rounded Reported	8 · UV-vis spectroscopy analysis · Fig. 9c
CG valence band position	-0.20 eV	—	—	Text Rounded Reported	8 · UV-vis spectroscopy analysis · Fig. 9

UV-vis diffuse reflectance spectroscopy

UV-visible and optical absorption spectroscopy

pure NiCo-MOF (NC) · Powder

BaSO4 reference background; indirect band gap from transformed UV-vis data

Context: pristine MOF control
Measurement source: 8 · UV-vis spectroscopy analysis · Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NC indirect band gap	2.30 eV	—	—	Text Rounded Reported	8 · UV-vis spectroscopy analysis · Fig. 9d
NC conduction band position	-0.99 eV	—	—	Text Rounded Reported	8 · UV-vis spectroscopy analysis · Fig. 9

XPS, in situ XPS, and UPS

X-ray photoelectron spectroscopy Ultraviolet photoelectron spectroscopy

NCCG-15 · Powder

full XPS/fine spectra of CG, NC, and NCCG-15; UPS spectra for CG and NC

Atmosphere: dark and illuminated XPS comparisons
Context: target composite with controls
Measurement source: 9 · XPS, in situ XPS and UPS analyses · Fig. 10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CG UPS cut-off energy	17.12 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10g
CG work functionMarked as a best value within this paper	7.42 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10g
NC UPS cut-off energy	18.96 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10h
NC work function	6.11 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10h
CG C 1s aromatic C=C peak	284.41 eV	—	—	Text Exact Reported	9 · XPS, in situ XPS and UPS analyses · Fig. 10b
CG C 1s conjugated dihexyne/CuC peak	285.04 eV	—	—	Text Exact Reported	9 · XPS, in situ XPS and UPS analyses · Fig. 10b
CG Cu 2p lower-binding-energy peak	932.96 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10d
NC O 1s carboxyl peak	531.12 eV	—	—	Text Exact Reported	10 · XPS, in situ XPS and UPS analyses · Fig. 10c