Spectroscopy — Two-Dimensional Conductive Metal-Organic Framework Reinforced Spinterface in Organic Spin Valves

6 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PcCu-Cu-30C MOF film · Thin Film

PcCu-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.

Temperature: 300
Geometry: Thin films
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 211 · Electronic structure and charge transport properties · Figures S12-S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Optical bandgap of PcCu-Cu film	1.22 eV	—	—	Text Exact Reported	211 · Electronic structure and charge transport properties · Supporting Information Figure S12
HOMO level of PcCu-Cu film	-5.27 eV	—	—	Text Exact Reported	S13 · Figure S13 · Figure S13
LUMO level of PcCu-Cu film	-4.05 eV	—	—	Calculated From Reported Exact Reported	S13 · Figure S14 · Figure S14

PcH2-Cu-30C MOF film · Thin Film

PcH2-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.

Temperature: 300
Geometry: Thin films
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 211 · Electronic structure and charge transport properties · Figures S12-S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Optical bandgap of PcH2-Cu filmMarked as a best value within this paper	1.00 eV	—	—	Text Exact Reported	211 · Electronic structure and charge transport properties · Supporting Information Figure S12
HOMO level of PcH2-Cu film	-5.21 eV	—	—	Text Exact Reported	S13 · Figure S13 · Figure S13
LUMO level of PcH2-Cu film	-4.21 eV	—	—	Calculated From Reported Exact Reported	S13 · Figure S14 · Figure S14

PcNi-Cu-30C MOF film · Thin Film

PcNi-Cu film; UV-vis/UPS electronic-structure measurement and derived LUMO.

Temperature: 300
Geometry: Thin films
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 211 · Electronic structure and charge transport properties · Figures S12-S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Optical bandgap of PcNi-Cu film	1.20 eV	—	—	Text Exact Reported	211 · Electronic structure and charge transport properties · Supporting Information Figure S12
HOMO level of PcNi-Cu film	-5.18 eV	—	—	Text Exact Reported	211 · Electronic structure and charge transport properties · Supporting Information Figure S13
LUMO level of PcNi-Cu film	-3.98 eV	—	—	Calculated From Reported Exact Reported	S13 · Figure S14 · Figure S14

PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film

Electronic structure of PcM-Cu films; UPS acquired at 300 K in SI.

Temperature: 300
Geometry: Thin films
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 211 · Electronic structure and charge transport properties · Figures S12-S14

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film

PcM-Cu films with different cycle numbers.

Geometry: Film on substrate
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 210-211 · Morphology and structural characterization · Figure 2a,d,g

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Absorbance growth marker	~307 nm absorbance increased with growth cycles	—	~	Text Approximate	210-211 · Morphology and structural characterization · Figure 2a,d,g

PcM-Cu-nC MOF film series (M = Ni, Cu, H2; n = 10-40 cycles) · Thin Film

Survey and high-resolution spectra of PcM-Cu-30C films.

Geometry: Thin film
Context: Pristine PcM-Cu MOF film controls.
Measurement source: 210-211 · Morphology and structural characterization · Figure 2b,e,h; Figure S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PcCu-Cu-30C and PcH2-Cu-30C XPS survey elements	C, N, O, and Cu only	—	—	Text Qualitative	210 · Morphology and structural characterization · Figure 2e,h
PcNi-Cu-30C XPS survey elements	C, N, O, Cu, and Ni only	—	—	Text Qualitative	210 · Morphology and structural characterization · Figure 2b
High-resolution Cu 2p3/2 prominent peak	~935 eV	—	~	Text Approximate	210 · Morphology and structural characterization · Supporting Information Figure S10a,c