Spectroscopy — Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver-Sulfur Networks

4 measurement groups · 9 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

free-standing Ag-BHT film · Thin Film

EPMA with JEOL JXA-8100; carbon by Flash EA 1112; silver by ICP-OES after dissolving samples in fuming nitric acid.

Context: pristine Ag-BHT composition assignment
Measurement source: S4, S17, S20 · Component characterization and analysis · Figure S17; Figure S18; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
found Ag mass percent	Ag 66.97%	—	—	Text Exact Reported	S4 · Synthesis of Ag-BHT film
found C mass percent	C 9.01%	—	—	Text Exact Reported	S4 · Synthesis of Ag-BHT film
found S mass percent	S 24.02%	—	—	Text Exact Reported	S4 · Synthesis of Ag-BHT film
EPMA Ag/S atom ratio sample 1	0.8201	—	—	SI Table Exact Reported	S20 · Table S2 · Table S2
EPMA Ag/S atom ratio sample 2	0.8132	—	—	SI Table Exact Reported	S20 · Table S2 · Table S2
EPMA Ag/S atom ratio sample 3	0.8494	—	—	SI Table Exact Reported	S20 · Table S2 · Table S2

free-standing Ag-BHT film · Thin Film

Tensor 27 Raman spectrometer, 100-3000 cm-1, 298 K.

Temperature: 298
Context: pristine and reduced Ag-BHT comparison
Measurement source: S5, S8, S11, S18 · Raman spectroscopic characterization · Figures S2, S8, S19

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BHT S-H Raman signal removed on coordination	BHT signal at approximately 2500 cm-1 disappears completely in Ag-BHT	—	—	Text Approximate	S5 · Raman spectroscopic characterization · Figure S2

free-standing Ag-BHT film · Thin Film

UPS of Ag-BHT film acquired at 300 K; Figure 5 compares pristine and reduced Ag-BHT.

Temperature: 300
Context: pristine film and reduced Ag-BHT comparison
Measurement source: p003 / 15155 · Results and discussion · Figure 4b; Figure 5

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
reduced Ag-BHT UPS behaviour	band gap in reduced Ag-BHT instead of a Fermi edge	—	—	Text Qualitative	p003 / 15155 · Results and discussion · Figure 5
pristine Ag-BHT Fermi edge	clear Fermi edge near top of valence band	—	—	Text Qualitative	p003 / 15155 · Results and discussion · Figure 4b

reduced Ag-BHT pellet · Pellet

XPS S 2p, Ag 3d, Li 1s and PXRD patterns compared between pristine and reduced Ag-BHT.

Context: reduced Ag-BHT compared with pristine Ag-BHT
Measurement source: p003-p004 / 15155-15156 · Results and discussion · Figures S13-S15

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source