Spectroscopy — Enhancement of Electrical Conductivity due to Structural Distortion from Linear to Nonlinear Dicarboxylato-Bridged Zn(II) 1D-Coordination Polymers

4 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FT-IR spectroscopy

Infrared spectroscopy

Compound 1 bulk crystals/powder · Single Crystal

KBr pellet; 4000-500 cm^-1 range.

Geometry: KBr pellet
Context: pristine compound 1 bulk sample
Measurement source: p002; SI page S2 · FT-IR spectroscopy · Figure S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
IR C=N stretch	1609 cm^-1	—	—	Text Exact Reported	p002; article page 2633 · Experimental Section - Synthesis · Figure S1
IR asymmetric COO stretch	1556 cm^-1	—	—	Text Exact Reported	p002; article page 2633 · Experimental Section - Synthesis · Figure S1
IR symmetric COO stretch	1319 cm^-1	—	—	Text Exact Reported	p002; article page 2633 · Experimental Section - Synthesis · Figure S1
IR water stretch	3252 cm^-1	—	—	Text Exact Reported	p002; article page 2633 · Experimental Section - Synthesis · Figure S1

UV-Vis absorption and Tauc/Kubelka-Munk band-gap analysis

UV-visible and optical absorption spectroscopy

Compound 1 ITO/compound/Al Schottky thin-film device · Thin Film

Solid-state electronic absorption spectra on PerkinElmer LAMBDA 25; optical characterisation with Shimadzu 2401 PC UV-vis over 250-800 nm; Tauc and Kubelka-Munk analyses reported.

Geometry: thin film
Context: pristine compound 1 thin film
Measurement source: p008-p010; SI pages S8-S10 · Materials and physical method; Optical bandgap from Kubelka-Munk · Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
UV absorption peak	337 nm	—	—	Text Exact Reported	p004; article page 2635 · Optical Characterization · Figure 4
band gap from Kubelka-Munk equation	3.61 eV	—	—	Text Rounded Reported	p010; SI page S10 · Optical bandgap from Kubelka-Munk · Figure S7
direct optical band gap from Tauc plotMarked as a best value within this paper	3.67 eV	—	—	Text Rounded Reported	p004-p005; article pages 2635-2636 · Optical Characterization · Figure 4