Thermoelectric — Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic framework

Measurement evidence

Thermoelectric

Solar-driven ionic power generation: Via a film of nanocellulose @ conductive metal-organic framework · Zhou S., Qiu Z., Stromme M. et al. · Energy and Environmental Science · 2021 · 900-905

4 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electronic Seebeck coefficient from open-circuit voltage versus temperature gradient

Freestanding CCM film · Thin Film

Dry CCM film; one side exposed to one sun for different intervals to generate thermal gradients.

Atmosphere
dry film under illumination
Geometry
dry CCM film with Au electrodes
Context
composite target sample
Measurement source
p017 · Supplementary Results · Fig. S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electronic Seebeck coefficient of CCMMarked as a best value within this paper-11.5 uV K-1Text
Exact Reported
p017 · Supplementary Results · Fig. S11c

Ionic thermoelectric voltage measurement in sealed coffee-bag arrangement

Freestanding CCM film · Thin Film

CCM film infiltrated with 0.01 M NaCl, pH 10; temperature difference 5 C between 17 and 22 C; water evaporation avoided.

Atmosphere
sealed aqueous electrolyte
Geometry
sealed warm-cold CCM film
Context
composite target sample
Measurement source
p004 · Solar-driven ionic power generation · Fig. 4c; Fig. S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ionic Seebeck coefficientMarked as a best value within this paper8.5 mV K-1Calculated From Reported
Exact Reported
p004 · Solar-driven ionic power generation · Fig. 4c
Ionic thermoelectric voltage under 5 C gradientMarked as a best value within this paper43 mV at 250 sText
Exact Reported
p004 · Solar-driven ionic power generation · Fig. 4c
Calculated ionic thermoelectric voltage under one sunapproximately 0.3 VCalculated From Reported
Approximate
p004 · Solar-driven ionic power generation · Fig. 4c

Streaming-potential I-V measurement after dropping electrolyte onto one side of CCM film

Freestanding CCM film · Thin Film

NaCl concentration and pH varied; wet-dry interface measured by source meter; evaporation rate varied with air blower.

Atmosphere
ambient aqueous electrolyte
Geometry
wet-dry interface across CCM film on quartz substrate
Context
composite target sample
Measurement source
p003-p004 · Solar-driven ionic power generation · Fig. 4a-b; Fig. S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Maximum ambient streaming potentialMarked as a best value within this paper0.35 V at pH 10 and 0.01 M NaClText
Exact Reported
p004 · Solar-driven ionic power generation · Fig. 4a
Predicted streaming-potential contribution under one sun0.85 V at 2.42 kg m-2 h-1Calculated From Reported
Rounded Reported
p004 · Solar-driven ionic power generation · Fig. 4b
Streaming voltage with pure waterapproximately 0.05 VText
Approximate
p004 · Solar-driven ionic power generation · Fig. S8

Thermal-conductivity estimation, UV-vis-NIR absorption, IR thermal imaging, solar simulator

Freestanding CCM film · Thin Film

Film floated on water at about 17 C and illuminated under one sun (1 kW m-2); surface temperature and thermal gradient recorded.

Atmosphere
ambient; one-sun illumination
Geometry
CCM film on floating water/polystyrene support
Context
composite target sample
Measurement source
p002-p003 · Solar thermal conversion · Fig. 2; Fig. S4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Solar-spectrum absorption>90% throughout solar spectrum rangeText
Approximate
p002 · Solar thermal conversion · Fig. 2a
Thermal gradient at film-water interfaceapproximately 35 CText
Approximate
p003 · Solar thermal conversion · Fig. 2b
Surface temperature after one-sun illuminationapproximately 51 C in 10 minText
Approximate
p002 · Solar thermal conversion · Fig. 2b
Calculated overall thermal conductivity of CCM film0.039 W m-1 K-1Calculated From Reported
Rounded Reported
p011 · Supplementary Results · Fig. S4 discussion
Measured in-plane thermal conductivity of CCM filmMarked as a best value within this paper0.045 W m-1 K-1Text
Exact Reported
p003 · Solar thermal conversion · Fig. S4
Pure Ni-HITP thermal conductivity comparison0.2 W m-1 K-1Text
Rounded Reported
p010 · Supplementary Results · Fig. S4 discussion