Zhou S., Qiu Z., Stromme M. et al. · Energy and Environmental Science · 2021 · 900-905
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Interfacial Ni-HITP growth on cellulose is superior to direct blending because direct-blended CC-Ni-HITP nanopaper has high resistance and discontinuous charged surfaces.
Caveat: Direct-blend synthesis details are vague, so exact morphology-processing differences are not fully controlled from the text.
p004 · Solar-driven ionic power generation · Fig. S12 · Linked to 3 structured results
XPS deconvolution supports chemically bonded Ni-HITP nanolayers on cellulose via an interfacial growth approach.
Caveat: Assignment is based on XPS peak positions and comparison spectra, not direct bond imaging.
p008 · Supplementary Results · Fig. S2c · Linked to 4 structured results
Hierarchical porosity and hybrid composition lower thermal conductivity, enabling heat localisation and a stable thermal gradient for ionic thermoelectric output.
Caveat: Thermal-conductivity calculation uses assumptions for gas mean free path and interfacial thermal resistance.
p010-p011 · Supplementary Results · Fig. S4 · Linked to 3 structured results
Ni-HITP nanopores confine water clusters, reduce vaporisation enthalpy, and accelerate evaporation through the CCM film.
Caveat: Water-cluster mechanism is inferred from FTIR shifts and TGA-DSC comparisons rather than directly observed clusters.
p012-p013 · Supplementary Results · Fig. S5 · Linked to 4 structured results
Acidic or basic electrolyte dopes/charges the CCM pore surface, producing charged nanochannels that selectively transport counter-ions.
Caveat: Low-salt conductivity values are figure-axis estimates; mechanism is inferred from pH-dependent zeta potential and conductivity trends.
p003 · Charged nanochannels in the CCM film · Fig. 3 · Linked to 3 structured results
The high solar IPG voltage arises from combined streaming potential at the wet-dry interface and ionic thermoelectric voltage across the hot-cold interface.
Caveat: The one-sun ionic thermoelectric contribution is calculated from separated measurements and a voltage difference, not directly isolated during device operation.
p004-p005 · Solar-driven ionic power generation · Fig. 4; Fig. 5 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Direct-blended cellulose/Ni-HITP nanopaperBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni-HITP particles/cellulose compositeNi(II) in Ni-HITP particles · HITP; Cladophora cellulose | 2D · CompositeComposite nanopaper made by direct blending of cellulose with Ni-HITP particles; lacks continuous charged cMOF surfaces. | p018 · Supplementary Results · Fig. S12 |
| Cladophora cellulose nanofibre @ Ni-HITP conductive MOF film (CCM)Browse family: Ni₃(HITP)₂ / Ni–HITP | Ni-HITP/cellulose compositeNi(II) in Ni-HITP nanolayers · HITP; Cladophora cellulose nanofibres as substrate | 2D · CompositeCore-shell nanofibres with Ni-HITP coating Cladophora cellulose; stacked/interwoven fibres form a freestanding hierarchical porous film. | p002 · Preparation and characterization of the CCM film · Fig. 1 |
| Cladophora cellulose control film | cellulosecellulose nanofibres | unknown · Model SystemPristine cellulose nanofibre film used as substrate/control for morphology, thermal-conductivity, and water-evaporation comparisons. | p009 · Supplementary Results · Fig. S3 |
| Ni-HITP conductive metal-organic frameworkBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2Ni(II) · 2,3,6,7,10,11-hexaiminotriphenylene (HITP) | 2D · PristineLayered conductive MOF with ordered approximately 2 nm nanopores in a hexagonal arrangement; assigned by TEM/HRTEM and XRD reflections. | p002 · Preparation and characterization of the CCM film · Fig. 1 |
| Wood nanocellulose @ Ni-HITP filmBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni-HITP/wood nanocellulose compositeNi(II) in Ni-HITP · HITP; wood nanocellulose substrate | 2D · CompositeNi-HITP grown or deposited on wood nanocellulose; XRD and N2 sorption were reported in SI. | p020 · Supplementary Results · Fig. S15 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Pristine Cladophora cellulose filmresearch_0769__mat__cladophora_cellulose | Thin Film · Pristine Control · Model | Pristine cellulose film before Ni-HITP growth. | p009 · Supplementary Results · Fig. S3 |
| CC-Ni-HITP nanopaperresearch_0769__mat__cc_ni_hitp_blend | Thin Film · Pristine Control · Composite | Prepared by direct blending Cladophora cellulose with Ni-HITP particles. | p018 · Supplementary Results · Fig. S12 |
| CCM composition/thickness seriesresearch_0769__mat__ccm_film | Thin Film · Target Sample · Composite | CCM films with varied thickness and Ni-HITP content.1, 2, 5, and 10 um; 17.5 wt% and 35 wt% Ni-HITP | p021 · Supplementary Results · Fig. S16 |
| U-shaped CCM solar-driven IPG deviceresearch_0769__mat__ccm_film | Electrode · Target Sample · Composite | 1.0 cm x 0.2 cm CCM film bent to U-shape on polystyrene foam, sealed with Ag/AgCl gel electrodes, connected to graphite paper wires, floated on 0.01 M NaCl at pH 10.polystyrene foam | p005 · Proof-of-concept device · Fig. 5 |
| Freestanding CCM filmresearch_0769__mat__ccm_film | Thin Film · Target Sample · Composite | Ni-HITP nanolayers grown on carboxylated Cladophora cellulose nanofibres; vacuum-filtered, washed, dried, and peeled off as a freestanding film.PVDF membrane during filtration; peeled off after drying · approximately 5 um in main text; SI also studies 1, 2, 5, and 10 um films | p002 · Preparation and characterization of the CCM film · Fig. 1 |
| Pure Ni-HITP referenceresearch_0769__mat__ni_hitp | Unknown · Pristine Control · Pristine Framework | Pure Ni-HITP comparison used for XPS binding energy and thermal conductivity discussion. | p007-p008 · Supplementary Results · Fig. S2c |
| WNC@Ni-HITP filmresearch_0769__mat__wnc_ni_hitp | Thin Film · Pristine Control · Composite | Wood nanocellulose-based CCM analogue.wood nanocellulose | p020 · Supplementary Results · Fig. S15 |