UV-visible absorption and photoluminescence spectroscopy
Zn-Pn SURMOF-2 thin film · Thin Film
Absorption using Cary5000 UMA; PL excitation at 3.49 eV; steady-state and time-resolved fluorescence instrumentation in SI
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Zn-Pn absorption red-shift vs solvated Pn-linker | 50 meV | 0.05 eV | — | Text Rounded Reported | 3 · Results and discussion · Fig. 2a |
| PL excimer-like emission maximum | 1.93 eV | — | — | Text Exact Reported | 3 · Results and discussion · Fig. 2b; Fig. S7 |
| PL excimer-like lifetime | ~4 ns | — | — | Text Approximate | 3 · Results and discussion · Fig. 2b; Fig. S7 |
| PL monomer-like emission maximum | 2.19 eV | — | — | Text Exact Reported | 3 · Results and discussion · Fig. 2b; Fig. S7 |
| PL monomer-like lifetime | ~1 ns | — | — | Text Approximate | 3 · Results and discussion · Fig. 2b; Fig. S7 |