Electrochemistry Application — 4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation

Measurement evidence

Electrochemistry Application

4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation · Wang X., Kumar Ghosh M., Zhuang P. et al. · Inorganica Chimica Acta · 2024 · 121892

6 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Blank UV-light nitrofurazone degradation control monitored by UV-vis

NFZ blank without catalyst · Unknown

Same NFZ photolysis conditions as CP tests but without CP catalyst.

Geometry
solution control
Context
no catalyst
Measurement source
6 · 3.4 Photocatalytic activity · Figure 7f
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
blank pseudo-first-order rate constantk = 0.0174 min-1Visual Estimate
Approximate
6 · Figure 7f · Figure 7f

UV-light photocatalytic degradation of nitrofurazone monitored by UV-vis

CP 1 yellow block crystals · Single Crystal

10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.

Geometry
suspended powder photocatalyst
Context
pristine framework catalyst in NFZ solution
Measurement source
5-6 · 2.4 Photocatalysis method; 3.4 Photocatalytic activity · Figure 7; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
pseudo-first-order rate constantk = 0.0588 min-1Visual Estimate
Approximate
6 · Figure 7f · Figure 7f
NFZ photodegradation efficiency after 30 min81.2 %Table
Exact Reported
6-7 · 3.4 Photocatalytic activity · Table 2

UV-light photocatalytic degradation of nitrofurazone monitored by UV-vis

CP 2 purple block crystals · Single Crystal

10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.

Geometry
suspended powder photocatalyst
Context
pristine framework catalyst in NFZ solution
Measurement source
5-7 · 2.4 Photocatalysis method; 3.4 Photocatalytic activity · Figure 7; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
pseudo-first-order rate constantk = 0.0659 min-1Visual Estimate
Approximate
6 · Figure 7f · Figure 7f
NFZ photodegradation efficiency after 30 min84.3 %Table
Exact Reported
6-7 · 3.4 Photocatalytic activity · Table 2

UV-light photocatalytic degradation of nitrofurazone monitored by UV-vis

CP 3 pink block crystals · Single Crystal

10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.

Geometry
suspended powder photocatalyst
Context
pristine framework catalyst in NFZ solution
Measurement source
5-7 · 2.4 Photocatalysis method; 3.4 Photocatalytic activity · Figure 7; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
pseudo-first-order rate constantk = 0.0729 min-1Visual Estimate
Approximate
6 · Figure 7f · Figure 7f
NFZ photodegradation efficiency after 30 min88.1 %Table
Exact Reported
6-7 · 3.4 Photocatalytic activity · Table 2

UV-light photocatalytic degradation of nitrofurazone monitored by UV-vis

CP 4 green block crystals · Single Crystal

10 mg finely ground CP, 50 mL 25 mg/L NFZ aqueous solution, 30 min dark adsorption, 400 W Hg lamp with mean wavelength 365 nm, aliquots every interval, 30 min irradiation.

Geometry
suspended powder photocatalyst
Context
pristine framework catalyst in NFZ solution
Measurement source
5-7 · 2.4 Photocatalysis method; 3.4 Photocatalytic activity · Figure 7; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
pseudo-first-order rate constantMarked as a best value within this paper0.0875 min-1Text
Exact Reported
7 · 3.4 Photocatalytic activity · Figure 7f
NFZ photodegradation efficiency after 30 minMarked as a best value within this paper92.2 %Table
Exact Reported
6-7 · 3.4 Photocatalytic activity · Table 2

Radical scavenger trapping experiments for CP 4 photocatalysis

CP 4 green block crystals · Single Crystal

NFZ + CP 4 under similar photocatalysis conditions with TBA (0.2 mL), BQ (10 mg), or AO (10 mg).

Geometry
suspended powder photocatalyst with scavenger
Context
pristine framework catalyst in scavenger-containing NFZ solution
Measurement source
7-8 · 3.5 Trapping experiments · Figure 9
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
rate constant with AO scavenger0.0664 min-1Text
Exact Reported
7 · 3.5 Trapping experiments · Figure 9
rate constant with BQ scavenger0.0123 min-1Text
Exact Reported
7 · 3.5 Trapping experiments · Figure 9
rate constant with TBA scavenger0.0578 min-1Text
Exact Reported
7 · 3.5 Trapping experiments · Figure 9