Measurement evidence
4′-((4-cyanobenzyl)oxy)-[1,1′-biphenyl] -4-carboxylic acid based Cd(II), Co(II), Mn(II) and Ni(II) coordination polymers as photocatalyst for nitrofurazone degradation · Wang X., Kumar Ghosh M., Zhuang P. et al. · Inorganica Chimica Acta · 2024 · 121892
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
CP 1 yellow block crystals · Single Crystal
CP 1 PXRD compared before synthesis/use and after photocatalysis; SI Figure S2 shows simulated, synthesized, and after-photodegradation traces.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD peak-position stability after photocatalysis | unaltered peak positions after photocatalysis | — | — | Text Qualitative | 7 · 3.4 Photocatalytic activity · Figure S2 |
CP 2 purple block crystals · Single Crystal
CP 2 PXRD compared before synthesis/use and after photocatalysis; SI Figure S2 shows simulated, synthesized, and after-photodegradation traces.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD peak-position stability after photocatalysis | unaltered peak positions after photocatalysis | — | — | Text Qualitative | 7 · 3.4 Photocatalytic activity · Figure S2 |
CP 3 pink block crystals · Single Crystal
CP 3 PXRD compared before synthesis/use and after photocatalysis; SI Figure S2 shows simulated, synthesized, and after-photodegradation traces.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| PXRD peak-position stability after photocatalysis | unaltered peak positions after photocatalysis | — | — | Text Qualitative | 7 · 3.4 Photocatalytic activity · Figure S2 |
CP 4 green block crystals · Single Crystal
CP 4 recovered after each photocatalytic cycle, washed repeatedly with double-distilled water, dried, reused for four total cycles; PXRD after fourth cycle.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| recycling stability | retained photocatalytic activity over four cycles; no perceptible PXRD peak shift after fourth cycle | — | — | Text Qualitative | 7 · 3.4 Photocatalytic activity · Figure 8 |
CP 1 yellow block crystals · Single Crystal
293 K; triclinic P-1 structure; CCDC 2289219.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bond valence sum | 2.05 | — | — | Table Exact Reported | 2 · Table 1 · Table 1 |
| cell length a | 5.5344(8) | — | (8) | Text Exact Reported | CIF |
| cell length b | 17.109(2) | — | (2) | Text Exact Reported | CIF |
| cell length c | 26.201(3) | — | (3) | Text Exact Reported | CIF |
| unit-cell volume | 2461.6(5) | — | (5) | Text Exact Reported | CIF |
| Cd-O/N coordination bond distance range | 2.291-2.344 A | — | individual distances carry parenthetical esd values in SI table | SI Table Range | 3 · Supplementary crystallographic tables · Table S2 |
| crystallographic formula | C60 H46 Cd N6 O8 | — | — | Text Exact Reported | CIF |
| R1 for observed reflections | 0.0601 | — | — | Text Exact Reported | CIF |
| space group | P -1 | — | — | Text Exact Reported | CIF |
CP 2 purple block crystals · Single Crystal
293 K; triclinic P-1 structure; CCDC 2289220.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bond valence sum | 2.08 | — | — | Table Exact Reported | 2 · Table 1 · Table 1 |
| cell length a | 5.4750(13) | — | (13) | Text Exact Reported | CIF |
| cell length b | 15.163(4) | — | (4) | Text Exact Reported | CIF |
| cell length c | 16.678(4) | — | (4) | Text Exact Reported | CIF |
| unit-cell volume | 1228.3(5) | — | (5) | Text Exact Reported | CIF |
| Co-O/N coordination bond distance range | 2.118-2.154 A | — | individual distances carry parenthetical esd values in SI table | SI Table Range | 3-4 · Supplementary crystallographic tables · Table S3 |
| crystallographic formula | C60 H46 Co N6 O8 | — | — | Text Exact Reported | CIF |
| R1 for observed reflections | 0.0792 | — | — | Text Exact Reported | CIF |
| space group | P -1 | — | — | Text Exact Reported | CIF |
CP 3 pink block crystals · Single Crystal
293 K; triclinic P-1 structure; CCDC 2289221.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bond valence sum | 2.03 | — | — | Table Exact Reported | 2 · Table 1 · Table 1 |
| cell length a | 5.4601(6) | — | (6) | Text Exact Reported | CIF |
| cell length b | 16.9710(19) | — | (19) | Text Exact Reported | CIF |
| cell length c | 26.591(3) | — | (3) | Text Exact Reported | CIF |
| unit-cell volume | 2443.0(5) | — | (5) | Text Exact Reported | CIF |
| Mn-O/N coordination bond distance range | 2.1751-2.273 A | — | individual distances carry parenthetical esd values in SI table | SI Table Range | 4 · Supplementary crystallographic tables · Table S4 |
| crystallographic formula | C60 H46 Mn N6 O8 | — | — | Text Exact Reported | CIF |
| R1 for observed reflectionsMarked as a best value within this paper | 0.0548 | — | — | Text Exact Reported | CIF |
| space group | P -1 | — | — | Text Exact Reported | CIF |
CP 4 green block crystals · Single Crystal
293 K; triclinic P-1 structure; CCDC 2289222.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| bond valence sum | 1.98 | — | — | Table Exact Reported | 2 · Table 1 · Table 1 |
| cell length a | 5.4445(9) | — | (9) | Text Exact Reported | CIF |
| cell length b | 16.802(3) | — | (3) | Text Exact Reported | CIF |
| cell length c | 26.928(4) | — | (4) | Text Exact Reported | CIF |
| unit-cell volume | 2439.2(7) | — | (7) | Text Exact Reported | CIF |
| Ni-O/N coordination bond distance range | 2.083-2.111 A | — | individual distances carry parenthetical esd values in SI table | SI Table Range | 4 · Supplementary crystallographic tables · Table S5 |
| crystallographic formula | C60 H46 N6 Ni O8 | — | — | Text Exact Reported | CIF |
| R1 for observed reflections | 0.0700 | — | — | Text Exact Reported | CIF |
| space group | P -1 | — | — | Text Exact Reported | CIF |