cMOF Evidence Base
Spectroscopy — Reaction-Type-Dependent Behavior of Redox-Hopping in MOFs─Does Charge Transport Have a Preferred Direction?

Measurement evidence

Spectroscopy

Reaction-Type-Dependent Behavior of Redox-Hopping in MOFs─Does Charge Transport Have a Preferred Direction? · Yan M., Bowman Z., Knepp Z.J. et al. · Journal of Physical Chemistry Letters · 2024 · 11919-11926

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

1H NMR after acid digestion

Nuclear magnetic resonance

Ru-NU-1000 particles · Powder

~3 mg Ru-NU-1000 digested with ~5 drops concentrated H2SO4 in 600 uL d6-DMSO; heated at 80 C for 1 h, cooled, sonicated, and measured by 1H NMR.

Temperature
353 for digestion; measurement temperature not reported
Atmosphere
not reported
Geometry
acid-digested MOF solution
Context
Ru loading quantification in target MOF.
Measurement source
p003 · Determination of SALI loading level · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Anchored Ru loading interpretationMarked as a best value within this paperone Ru complex anchored to each Zr node——Text
Approximate		p003 · Determination of SALI loading level · Figure S5
Ru complex to H4TBAPy linker ratio~2:1 Ru complex:linker——Text
Approximate		p003 · Determination of SALI loading level · Figure S5
Ru complex to Zr node ratio~1:1 Ru complex:Zr node——Text
Approximate		p003 · Determination of SALI loading level · Figure S5

UV-vis spectroscopy

UV-visible and optical absorption spectroscopy

[RuII(bpy)2(bpy-COOH)](PF6)2 homogeneous solution · Model

UV-vis spectra of [RuII(bpy)2(bpy-COOH)](PF6)2 at 1.0e-5 to 3.0e-5 M concentrations.

Atmosphere
solution; solvent not explicitly stated in caption
Geometry
solution spectroscopy
Context
Molecular Ru-complex characterisation.
Measurement source
p002 · Spectroscopy of [RuII(bpy)2(bpy-COOH)](PF6)2 · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Ru complex UV-vis labelled band456 nm——Figure Axis
Rounded Reported		p002 · Spectroscopy · Figure S3