Spectroscopy — Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers

8 measurement groups · 38 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

CoHg(C7H4NS2)4(phen) · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	240-244 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1417 s, 1145 m, 994 s, 650 w, 434 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	5.2 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	480 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	1.03 g, 94%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

CoHg(C7H4NS2)4(phen)3 · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	255-257 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1419 s, 994 s, 650 w, 430 s cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	4.95 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	470 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	1.33 g, 91%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

NiZn(C7H4NS2)4(en) · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	274-276 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1394 s, 1086 m, 1602 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	3.1 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	620 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	0.79 g, 94%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

NiZn(C7H4NS2)4(en)3 · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	260-262 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1373 s, 1084, 1126, 1618 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	2.9 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	600 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	0.92 g, 96%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

NiZn(C7H4NS2)4(phen) · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	285-287 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1383 s, 1253 m, 1086 m, 645 w, 430 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	3.2 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	650 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	0.89 g, 92%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

NiZn(C7H4NS2)4(phen)3 · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	248-250 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1369 s, 1116 s, 1032 m, 645 w, 440 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	2.9 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	480, 640 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	1.16 g, 88%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

Elemental analysis, IR (KBr), UV-visible (Nujol), magnetic susceptibility, decomposition point

Infrared spectroscopy UV-visible and optical absorption spectroscopy Magnetometry and magnetic susceptibility Bulk elemental and compositional analysis

NiZn(C7H4NS2)4(py)2 · Powder

solid product characterization after precipitation

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental - Synthesis of the complexes

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
decomposition point	274-276 deg C	—	—	Text Range	2 · Experimental - Synthesis of the complexes
selected IR bands	1385 s, 1086 s, 620 m, 430 m cm^-1	—	—	Text Rounded Reported	2 · Experimental - Synthesis of the complexes
effective magnetic moment	2.9 B.M.	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
UV-visible absorption maxima	630 nm	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes
isolated yield	0.88 g, 93%	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

IR spectra and UV-visible/magnetic moment interpretation

Infrared spectroscopy UV-visible and optical absorption spectroscopy

all products reported in this paper · Pellet

structure assignment from ligand bands, ring deformation bands, N-H bending, and electronic transitions

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Results and discussion

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
cobalt coordination environment	octahedral environment around cobalt(II)	—	—	Text Qualitative	3 · Results and discussion
nickel coordination environment	octahedral coordination around nickel(II)	—	—	Text Qualitative	3 · Results and discussion
coordination mode	N,S(exocyclic) coordination of C7H4NS2- predicted	—	—	Text Qualitative	3 · Results and discussion