Electrical Transport — Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers

Measurement evidence

Electrical Transport

Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers · Singh N., Kumar Sinha R. · Inorganic Chemistry Communications · 2002 · 255-258

15 measurement groups · 25 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state conductivity

Electrical conductivity

all products reported in this paper · Pellet

series-level room-temperature conductivity range and activation energy from 303-383 K pellet data

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 1 · Abstract

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
activation energy range	Ea in the 0.58-1.75 eV range	1.75 eV	—	Text Range	3 · Electrical conductivity
room-temperature conductivity range except py2	10^-12-10^-5 S cm^-1	0.00001 S cm^-1	—	Text Range	1 · Abstract
temperature range for semiconducting behaviour	303-383 K	383 K	—	Text Range	3 · Electrical conductivity

solid-state conductivity of pressed pellet

Electrical conductivity

CoHg(C7H4NS2)4(phen) · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature conductivityMarked as a best value within this paper	10^-5 S cm^-1	—	—	Text Approximate	3 · Electrical conductivity
log10 conductivity near 303 K	log sigma approximately -5.2 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -4.1 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

CoHg(C7H4NS2)4(phen)3 · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature conductivity	10^-6 S cm^-1	—	—	Text Approximate	3 · Electrical conductivity
log10 conductivity near 303 K	log sigma approximately -4.5 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -3.3 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

NiZn(C7H4NS2)4(en) · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
log10 conductivity near 303 K	log sigma approximately -12.0 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -6.0 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

NiZn(C7H4NS2)4(en)3 · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
log10 conductivity near 303 K	log sigma approximately -9.0 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -7.6 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

NiZn(C7H4NS2)4(phen) · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
log10 conductivity near 303 K	log sigma approximately -12.0 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -9.8 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

NiZn(C7H4NS2)4(phen)3 · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303-383 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity · Fig. 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
log10 conductivity near 303 K	log sigma approximately -12.2 at 1/T x 10^3 ~= 3.30 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1
log10 conductivity near 383 K	log sigma approximately -9.5 at 1/T x 10^3 ~= 2.61 K^-1	—	—	Figure Axis Approximate	3 · Electrical conductivity · Fig. 1

solid-state conductivity of pressed pellet

Electrical conductivity

NiZn(C7H4NS2)4(py)2 · Powder

room-temperature and temperature-dependent conductivity; 303-383 K plot for all except py2

Temperature: 303 K
Atmosphere: not specified
Geometry: pressed pellet
Context: pristine mixed-metal coordination compound
Measurement source: 3 · Electrical conductivity

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature conductivity classification	insulator at room temperature (303 K)	—	—	Text Qualitative	3 · Electrical conductivity

molar conductance

CoHg(C7H4NS2)4(phen) · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	57.50	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

CoHg(C7H4NS2)4(phen)3 · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	78.67	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

NiZn(C7H4NS2)4(en) · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	43.58	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

NiZn(C7H4NS2)4(en)3 · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	72.66	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

NiZn(C7H4NS2)4(phen) · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	24.22	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

NiZn(C7H4NS2)4(phen)3 · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	30.27	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes

molar conductance

NiZn(C7H4NS2)4(py)2 · Powder

DMSO solution; concentration reported as 10^-3 M in discussion

Atmosphere: not specified
Context: pristine mixed-metal coordination compound
Measurement source: 2 · Experimental and Results

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
molar conductance in DMSO	39.35	—	—	Text Exact Reported	2 · Experimental - Synthesis of the complexes