Synthesis · Synthesis, characterization and electrical conductivity of mixed-ligand heterobimetallic coordination polymers

7 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsCoHg(C7H4NS2)4 (0.923 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; 1,10-phenanthroline added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CoHg(C7H4NS2)4	0.923 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	1,10-phenanthroline	0.198 g, 1 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 2: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsCoHg(C7H4NS2)4 (0.923 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; 1,10-phenanthroline added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CoHg(C7H4NS2)4	0.923 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	1,10-phenanthroline	0.594 g, 3 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 3: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsNiZn(C7H4NS2)4 (0.788 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; ethylenediamine added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	NiZn(C7H4NS2)4	0.788 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	ethylenediamine	0.060 g, 1 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 4: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsNiZn(C7H4NS2)4 (0.788 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; ethylenediamine added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	NiZn(C7H4NS2)4	0.788 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	ethylenediamine	0.180 g, 3 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 5: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsNiZn(C7H4NS2)4 (0.788 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; 1,10-phenanthroline added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	NiZn(C7H4NS2)4	0.788 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	1,10-phenanthroline	0.198 g, 1 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 6: Other

2 · Experimental - Synthesis of the complexes

Metal precursorsNiZn(C7H4NS2)4 (0.788 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; 1,10-phenanthroline added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	NiZn(C7H4NS2)4	0.788 g, 1 mmol	2 · Experimental - Synthesis of the complexes
Linker	1,10-phenanthroline	0.594 g, 3 mmol · in 5 cm3 ethanol	2 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	2 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	2 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	2 · Experimental - Synthesis of the complexes

Partial recipeSource: Main

Route 7: Other

1 · Experimental - Synthesis of the complexes

Metal precursorsNiZn(C7H4NS2)4 (0.788 g, 1 mmol); precursor itself prepared from metal salt solutions as in reference [10]

Linker precursorspotassium 2-sulfanylbenzothiazolate used to prepare precursor; pyridine added as neutral ligand

Solvents50 cm3 ethanol-water (90:10 v/v) for precursor suspension; 5 cm3 ethanolic ligand solution

Atmospherenot specified

Temperatureroom temperature

Timeovernight (exact hours not specified)

Work-upfiltered coloured precipitate; washed with ethanol then Et2O; dried in vacuo over CaCl2

Activationdried in vacuo over CaCl2; no framework activation reported

Scalability contextmillimole-scale precipitation synthesis; no scale-up data

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	NiZn(C7H4NS2)4	0.788 g, 1 mmol	1 · Experimental - Synthesis of the complexes
Linker	pyridine	0.158 g, 2 mmol · in 5 cm3 ethanol	1 · Experimental - Synthesis of the complexes
Solvent	C2H5OH-H2O (90:10 v/v)	50 cm3	1 · Experimental - Synthesis of the complexes
Solvent	ethanol	5 cm3 · ligand solution	1 · Experimental - Synthesis of the complexes
Other	CaCl2	not specified · drying agent	1 · Experimental - Synthesis of the complexes