Spectroscopy — Highly Selective and Sensitive Detection of Volatile Sulfur Compounds by Ionically Conductive Metal-Organic Frameworks

5 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode

Cu-TCPP IC-MOF thin film compared with H2TCPP precursor

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-TCPP FTIR new peak	1400 cm-1	—	—	Text Rounded Reported	main p.3 · Results and Discussion · Figure 2a
Cu-TCPP FTIR new peak	1620 cm-1	—	—	Text Rounded Reported	main p.3 · Results and Discussion · Figure 2a
H2TCPP carboxyl peak nearly disappeared after Cu-TCPP formation	peak around 1700 cm-1 almost completely disappeared	—	—	Text Approximate	main p.3 · Results and Discussion · Figure 2a

Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode

Cu 2p and S 2p spectra before/after CH3SH detection on Cu-TCPP IC-MOF

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
After CH3SH detection S 2p peak	around 168 eV	—	—	Text Approximate	main p.6 · Results and Discussion · Figure S13

Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode

Cu 2p and S 2p spectra before/after H2S detection on Cu-TCPP IC-MOF

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Before detection Cu-O Cu 2p1/2 peak	934.8 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5a
Before detection Cu-O Cu 2p3/2 peak	954.9 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5a
After H2S detection Cu-S Cu 2p peak	932.5 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5a
After H2S detection Cu-S Cu 2p peak	952.4 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5a
After H2S detection S 2p Cu-S peak	162.3 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5b
After H2S detection S 2p Cu-S peak	163.3 eV	—	—	Text Exact Reported	main p.6 · Results and Discussion · Figure 5b

Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode

H2TCPP, Cu-TCPP IC-MOF, and Cu(NO3)2 compared

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

Cu-TCPP IC-MOF thin-film sensor on ITO interdigital electrodes · Electrode

H2TCPP and Cu-TCPP IC-MOF spectra compared

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-TCPP Q-band simplified to one peak	Cu-TCPP IC-MOF shows only one peak in Q-band region (500-700 nm)	—	—	Text Qualitative	main p.3 · Results and Discussion · Figure 2b