Spectroscopy — Tarnishing Silver Metal into Mithrene

5 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

[AgSePh]inf thin films on glass coverslips · Thin Film

Confocal maps with 405 nm excitation; representative PL spectra for glass coverslip films of varying Ag precursor thickness

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Confocal-map excitation wavelength	405 nm	405 nm	—	Caption Exact Reported	S-4 · Figure S3 caption · Figure S3
Uniform blue emission wavelength in SI glass-film mapsMarked as a best value within this paper	467 nm	467 nm	—	Caption Exact Reported	S-4 · Figure S3 caption · Figure S3
SI Figure S4 peak intensity versus silver thickness fit	R2 = 0.9106	0.9106	—	Figure Axis Approximate	S-4 · Figure S4 · Figure S4b

Tarnished [AgSePh]inf thin film on silver · Thin Film

PL emission spectra of solution-grown [AgSePh]inf crystals and tarnished films; excitation wavelength 350-380 nm for spectrometer measurements

Context: Pristine [AgSePh]inf film compared with solution-grown pristine crystallites
Measurement source: 13893 · Results and Discussion · Figure 3b,d,e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Photoluminescence emission peak of tarnished filmsMarked as a best value within this paper	467 nm	467 nm	—	Text Exact Reported	13893 · Results and Discussion · Figure 3e

Low-yield [AgSePh]inf from silver films immersed in DPSe/toluene · Thin Film

Silver films immersed in DPSe/toluene for three days; local blue luminescent product analysed

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Emission peak from low-yield toluene immersion product	467 nm	467 nm	—	Caption Exact Reported	S-3 · Figure S2 caption · Figure S2c,f

[AgSePh]inf thin films on glass coverslips · Thin Film

Absorption spectra of glass-supported films before and after 3 days tarnishing; Ag precursor thicknesses 1-10 nm

Geometry: Transmission through glass coverslips
Context: Pristine [AgSePh]inf thin films compared with unreacted Ag films
Measurement source: 13896 · Thin Films on Glass Substrates for Optical Characterization · Figure 7b,c

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Linear fit of 434 nm absorption versus [AgSePh]inf layersMarked as a best value within this paper	r2 = 0.998	0.998	—	Text Exact Reported	13896 · Thin Films on Glass Substrates for Optical Characterization · Figure 7c inset
[AgSePh]inf density used in film-thickness conversion estimate	2.7 g/cm3	2.7 g/cm3	—	Text Exact Reported	13896 · Thin Films on Glass Substrates for Optical Characterization
Absorption feature used for layer-count scalingMarked as a best value within this paper	434 nm	434 nm	—	Text Exact Reported	13896 · Thin Films on Glass Substrates for Optical Characterization · Figure 7c
Large-area film size	>6 cm2	6 cm2	—	Text Approximate	13892 · Abstract
Silver density used in film-thickness conversion estimate	10.5 g/cm3	10.5 g/cm3	—	Text Exact Reported	13896 · Thin Films on Glass Substrates for Optical Characterization

[AgSePh]inf film from 100 nm Ag on silicon under humidity variants · Thin Film

Diffuse reflectance spectra of control, dry, room-air, and air-plus-water tarnishing experiments on silicon-supported 100 nm Ag films

Atmosphere: Dry/Drierite, room air, or water-saturated reaction vessel during synthesis
Geometry: Reflectance from thin films on silicon
Context: Pristine [AgSePh]inf tarnished films compared with no-DPSe and dry controls
Measurement source: 13894 · Water's Role in Silver Tarnishing by Diphenyl Diselenide · Figure 4e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Absorption peak in tarnished humidity-test samplesMarked as a best value within this paper	434 nm	434 nm	—	Text Exact Reported	13894 · Water's Role in Silver Tarnishing by Diphenyl Diselenide · Figure 4e
Dry atmosphere inactivates tarnishing reaction	desiccated and control samples nearly indistinguishable by optical reflectivity	—	—	Text Qualitative	13894 · Water's Role in Silver Tarnishing by Diphenyl Diselenide · Figure 4e