Spectroscopy — Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper Anodes

5 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

AES spectrum and elemental maps of C, O and Cu.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
AES carbon peak	about 274.2 eV	—	—	Caption Approximate	SI p.S19 · Section 15 · Figure S19
AES copper peak	about 890.5 eV	—	—	Caption Approximate	SI p.S19 · Section 15 · Figure S19
AES oxygen peak	about 505.6 eV	—	—	Caption Approximate	SI p.S19 · Section 15 · Figure S19

Cu3(BTPA)2 MOF film prepared by EC method · Thin Film

XPS spectra and TEM images of three secondary EC-grown films.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu3(BTPA)2 lattice spacing	about 1.3 nm	—	—	Text Approximate	main p.4 · Generality of EC method · Figure 5j
Cu2(MTCP) lattice spacing	about 1.6 nm	—	—	Text Approximate	main p.4 · Generality of EC method · Figure 5k
B 1s core-level peak in secondary films	191.2 eV	—	—	Text Exact Reported	main p.4 · Generality of EC method · Figure 5g-i
C 1s core-level peak in secondary films	about 285.4 eV	—	—	Text Approximate	main p.4 · Generality of EC method · Figure 5g-i
Cu 2p core-level peak in secondary films	935.1 eV	—	—	Text Exact Reported	main p.4 · Generality of EC method · Figure 5g-i
N 1s core-level peak in secondary films	398.8 eV	—	—	Text Exact Reported	main p.4 · Generality of EC method · Figure 5g-i
O 1s core-level peak in secondary films	533.2 eV	—	—	Text Exact Reported	main p.4 · Generality of EC method · Figure 5g-i
Cu3(TBTC)2 lattice spacing	about 1.3 nm	—	—	Text Approximate	main p.4 · Generality of EC method · Figure 5l

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

Film spectrum compared with powder; Raman mapping at 1345 and 1566 cm-1.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Raman mapping band	1345 cm-1	—	—	Caption Rounded Reported	SI p.S16 · Section 12 · Figure S16
Raman mapping band	1566 cm-1	—	—	Caption Rounded Reported	SI p.S16 · Section 12 · Figure S16

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

Cu3(HHTP)2 MOF film, Cu3(HHTP)2 powder and HHTP ligand spectra.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP intrinsic absorption peak	254 nm	—	—	Text Exact Reported	SI p.S17 · Section 13 · Figure S17
Ligand-to-metal charge-transfer absorption peak	622 nm	—	—	Text Exact Reported	SI p.S17 · Section 13 · Figure S17
*Aromatic pi-pi absorption peak**	356 nm	—	—	Text Exact Reported	SI p.S17 · Section 13 · Figure S17

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

XPS survey plus C1s and Cu2p spectra for Cu3(HHTP)2 film; powder comparison in Figure S18.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C 1s C-C binding energy	284.5 eV	—	—	Text Exact Reported	main p.2 · XPS characterisation · Figure 1h
C 1s C-O binding energy	285.8 eV	—	—	Text Exact Reported	main p.2 · XPS characterisation · Figure 1h
Cu 2p1/2 binding energy	about 954 eV	—	—	Text Approximate	main p.2 · XPS characterisation · Figure 1i
Cu 2p3/2 binding energy	about 935 eV	—	—	Text Approximate	main p.2 · XPS characterisation · Figure 1i