Electrochemistry Application — Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper Anodes

Measurement evidence

Electrochemistry Application

Electrochemical Synthesis of Large Area Two-Dimensional Metal–Organic Framework Films on Copper Anodes · Liu Y., Wei Y., Liu M. et al. · Angewandte Chemie - International Edition · 2021 · 2887-2891

2 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Electrolytic current and calculated Cu electrolysis rate versus applied potential

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

Electrolysis rate V_Cu2+ calculated from Q = It = 2 n_Cu2+ F and divided by surface area and time.

Atmosphere
EC atmosphere not stated
Geometry
Cu foil anode in EC cell
Context
Synthesis electrochemistry for pristine film
Measurement source
SI p.S7-S8 · Sections 6-7 · Figures S5-S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
High electrolysis rate producing particles7.85 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7d
High electrolysis rate producing particles10.55 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7e
Highest electrolysis rate producing particles12.82 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7f
Low electrolysis rate supporting film growth2.582 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7a
Electrolysis rate morphology point4.061 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7b
Electrolysis rate morphology point5.33 x 10^-10 mol cm-2 s-1Caption
Exact Reported
SI p.S8 · Section 7 · Figure S7c
Cu oxidation threshold voltageabove 0.13 VText
Approximate
main p.3 · Growth mechanism · Figure S5

Chronoamperometric I-t growth curve

As-grown Cu3(HHTP)2 MOF film on single-crystal Cu(100) anode · Thin Film

Electrolysis at 0.4 V; stages labelled ion migration, stable growth, growth inhibition and stagnant growth.

Geometry
Cu anode EC cell
Context
Synthesis electrochemistry for pristine film
Measurement source
SI p.S11 · Section 9 · Figure S10
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Four I-t growth stages at 0.4 Vion migration, stable growth, growth inhibition, stagnant growthCaption
Qualitative
SI p.S11 · Section 9 · Figure S10