Spectroscopy — Semiconductive Coordination Polymer with Multi-Channel Charge Transfer for High-Performance Direct X-ray Detection

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

as-synthesised orange plate single crystals of 1 · Single Crystal

400 nm pump; supercontinuum probe; main Figure 2 at 260 nJ; SI includes different laser powers.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
excited-state absorption band of compound 1	580 nm	—	—	Text Exact Reported	3 · Results and Discussion · Figure 2a
fs-TA lifetime stage 1 for compound 1	0.535 ps	—	—	SI Table Exact Reported	S19 · Supplementary Tables · Table S3
fs-TA lifetime stage 2 for compound 1	3.985 ps	—	—	SI Table Exact Reported	S19 · Supplementary Tables · Table S3
fs-TA lifetime stage 3 for compound 1	38.007 ps	—	—	SI Table Exact Reported	S19 · Supplementary Tables · Table S3
fs-TA lifetime stage 4 for compound 1	3261.250 ps	—	—	SI Table Exact Reported	S19 · Supplementary Tables · Table S3

as-synthesised orange plate single crystals of 1 · Single Crystal

PL spectra from 80 to 360 K; Arrhenius fit of integrated PL intensity.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
exciton binding energy EbMarked as a best value within this paper	46.34 meV	0.04634 eV	—	Text Exact Reported	5 · Results and Discussion · Figure 3e

as-synthesised orange plate single crystals of 1 · Single Crystal

Room-temperature diffuse reflectance using BaSO4 reference on PerkinElmer Lambda 950 with integrating sphere.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
optical band gap from Tauc plot	approximately 2.11 eV	—	—	Text Approximate	4 · Results and Discussion · Figure S6