Yu X.-Q., Sun L.-B., Li Q.-Y. et al. · Angewandte Chemie - International Edition · 2025 · e202419266
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The detector maintains favourable ambient-air/moisture stability and operational cycling stability.
Caveat: Cycle and drift values are device-level tests; long-term ambient claim is three-month exposure rather than continuous operation under all conditions.
7 · Results and Discussion · Figure 4e-g; Figure S1; Figure S13 · Linked to 5 structured results
The Ag/1/Ag pellet detector achieves 8.05 x 10^-3 cm2 V^-1 mobility-lifetime product, 172 μC Gyair^-1 cm^-2 sensitivity at 35 V, and 0.128 μGyair s^-1 measured low-dose response, reported as record or superior values among CP-based direct X-ray detectors.
Caveat: Leaderboard claim relies on the authors' literature comparison in Table S6; no external documents were fetched by protocol.
1, 7 · Abstract; Results and Discussion · Figure 4; Table S6 · Linked to 4 structured results
Compound 1 is a phase-pure triclinic P-1 Co(II) coordination polymer in which DIPA-bridged 2D layers are assembled into a 3D framework by BPTTz ligands.
Caveat: Lattice solvent is described as highly disordered.
2-3 · Results and Discussion · Figure 1; Table S1 · Linked to 3 structured results
The pellet detector has high bulk resistivity and pA-level dark current, supporting low-noise X-ray detection.
Caveat: Dark-current magnitude is visually estimated from Figure 3d; resistivity is directly reported.
4-5 · Results and Discussion · Figure 3b-d · Linked to 3 structured results
Ligand-mediated electronic-state regulation and compact BPTTz/DIPA interactions create multiple charge-transfer pathways that reduce carrier recombination/quenching.
Caveat: Mechanistic attribution combines spectroscopy and calculations; direct device performance is measured, but pathway assignment is interpretive.
3-4 · Results and Discussion · Figure 2; Table S3-S4 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| {[Co(BPTTz)(DIPA)]·DMA}n (compound 1) | C26H19CoI2N5O5S2; reported polymer formula {[Co(BPTTz)(DIPA)]·DMA}nCo(II) ions octahedrally coordinated by four carboxylate O atoms from DIPA2- ligands and two N atoms from BPTTz ligands · BPTTz = 2,5-bis(pyridine-4-yl)thiazolo[5,4-d]thiazole; DIPA2- from H2DIPA = 2,5-diiodoterephthalic acid; lattice DMA | 3D · PristineTriclinic P-1; DIPA-bridged 2D layers assembled into a 3D framework through BPTTz ligands; highly disordered lattice DMA, two DMA molecules per unit cell. | 1-3 · Abstract; Results and Discussion · Figure 1; Table S1-S2 referenced |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| as-synthesised orange plate single crystals of 1research_0285__mat__m_co_bpttz_dipa_dma_1 | Single Crystal · Target Sample · Pristine Framework | Washed with water and DMA, dried in vacuum; all crystal samples selected under microscope. | S7 · 1.11 Syntheses · Figure S1 |
| DFT model of compound 1 from crystal structureresearch_0285__mat__m_co_bpttz_dipa_dma_1 | Model · Model System · Model | Crystallographic data of 1 used to build DFT and molecular models. | S5 · 1.5 Theoretical calculations · Figure 2; Table S4 |
| 1_moistureresearch_0285__mat__m_co_bpttz_dipa_dma_1 | Powder · Target Sample · Pristine Framework | As-prepared crystalline sample placed in the dark under 85%-100% relative humidity for 24 h. | S8 · 2 Supplementary Figures · Figure S1 |
| Ag/1/Ag pellet detector deviceresearch_0285__mat__m_co_bpttz_dipa_dma_1 | Pellet · Target Sample · Pristine Framework | Microcrystalline powder pressed in 3 x 3 mm2 mould at approximately 0.15 tons; silver paste contacts and silver wires.Ag contacts/silver paste on both sides · about 0.50 mm; SI also reports three pellets of about 0.50 mm, 0.50 mm, and 0.75 mm | S4 · 1.4 X-ray detection measurements · Figure 3; Figure 4 |
| Sample 2 pellet detectorresearch_0285__mat__m_co_bpttz_dipa_dma_1 | Pellet · Target Sample · Pristine Framework | Repeat pellet detector from same material batch/fabrication protocol.Ag contacts/silver paste · not specified for Sample 2; pellet set includes about 0.50, 0.50, and 0.75 mm | 7 · Results and Discussion · Figures S14-S15 |
| Sample 3 pellet detectorresearch_0285__mat__m_co_bpttz_dipa_dma_1 | Pellet · Target Sample · Pristine Framework | Repeat pellet detector from same material batch/fabrication protocol.Ag contacts/silver paste · not specified for Sample 3; pellet set includes about 0.50, 0.50, and 0.75 mm | S14-S15 · 2 Supplementary Figures · Figures S16-S17 |