Complete recipeSource: SI
Route 1: Solvothermal
S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1)
Metal precursorsCo(NO3)2·6H2O (0.125 mmol, 36.38 mg)
Linker precursorsBPTTz (0.0625 mmol, 18.5 mg); 2,5-diiodoterephthalic acid (H2DIPA, 0.0125 mmol, 52.24 mg)
Solventsdeionised water (2.5 mL); N,N'-dimethylacetamide (DMA, 7.5 mL)
Additives8 mol/L HNO3 solution (750 uL)
AtmosphereSealed 20 mL glass vial; atmosphere not otherwise stated
Temperature100
Time72
Work-upSlowly cooled to room temperature; orange plate single crystals washed with water and DMA.
ActivationDried in vacuum for tests.
Scalability contextSmall-vial solvothermal synthesis; yield 61.33% based on 2,5-diiodoterephthalic acid; pellet devices made by grinding and pressing crystals.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Co(NO3)2·6H2O | 0.125 mmol, 36.38 mg | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |
| Linker | 2,5-bis(pyridine-4-yl)thiazolo[5,4-d]thiazole (BPTTz) | 0.0625 mmol, 18.5 mg | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |
| Linker | 2,5-diiodoterephthalic acid (H2DIPA) | 0.0125 mmol, 52.24 mg | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |
| Solvent | deionized water | 2.5 mL | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |
| Solvent | N,N'-Dimethylacetamide (DMA) | 7.5 mL | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |
| Acid | HNO3 solution | 750 uL · 8 mol/L | S7 · 1.11 Syntheses of {[Co(BPTTz)(DIPA)]·DMA}n (1) |