Spectroscopy — Metal-halide porous framework superlattices

13 measurement groups · 23 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

circularly polarized luminescence

Photoluminescence and fluorescence spectroscopy

R-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal

linearly polarized 405-nm laser; power density 10 W cm-2 for Fig. 4h; 78 K

Temperature: 78
Geometry: single crystal
Context: chiral amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R-MBA/PbI2@PCN-606 CPL degree P	P = 27.7	—	—	Figure Axis Rounded Reported	423 · Fig. 4h and text · Fig. 4h

circularly polarized luminescence

Photoluminescence and fluorescence spectroscopy

S-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal

linearly polarized 405-nm laser; power density 10 W cm-2 for Fig. 4h; 78 K

Temperature: 78
Geometry: single crystal
Context: chiral amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-MBA/PbI2@PCN-606 CPL degree PMarked as a best value within this paper	P = -29.3	—	—	Figure Axis Rounded Reported	423 · Fig. 4h and text · Fig. 4h

circularly polarized luminescence

Photoluminescence and fluorescence spectroscopy

S-NEA/PbI2@PCN-606 amine-modified crystals · Single Crystal

linearly polarized 405-nm laser; power density 10 W cm-2 for Fig. 4h; 78 K

Temperature: 78
Geometry: single crystal
Context: chiral amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
R/S-NEA/PbI2@PCN-606 CPL degree P	about 28%	—	—	Text Approximate	423 · Fig. 4h and text · Fig. 4h

FTIR

Infrared spectroscopy

S-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal

KBr pellet FTIR; 400-4000 cm-1

Temperature: 298
Geometry: powder/single crystals
Context: amine-modified versus pristine and PbI2@PCN-606
Measurement source: 423 · Fig. 4 caption · Fig. 4e

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
FTIR C-N-H bending peak	700 cm-1	—	—	Figure Axis Rounded Reported	422-423 · Physical properties/Fig. 4e · Fig. 4e
FTIR N-H bending peak	1630 cm-1	—	—	Figure Axis Rounded Reported	422-423 · Physical properties/Fig. 4e · Fig. 4e

steady-state photoluminescence

Photoluminescence and fluorescence spectroscopy

S-MBA/PbI2@NU-1000 amine-modified crystals · Single Crystal

S-MBA/PbI2@MOF measured at 78 K; source data Fig. 4f

Temperature: 78
Geometry: single crystal
Context: amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-MBA/PbI2@MOF PL peak wavelength	505 nm at normalized maximum in source data	—	—	SI Table Exact Reported	source-data sheet Fig 4f · Fig. 4f source data · Fig. 4f

steady-state photoluminescence

Photoluminescence and fluorescence spectroscopy

S-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal

S-MBA/PbI2@MOF measured at 78 K; source data Fig. 4f

Temperature: 78
Geometry: single crystal
Context: amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-MBA/PbI2@MOF PL peak wavelengthMarked as a best value within this paper	602.5 nm at normalized maximum in source data	—	—	SI Table Exact Reported	source-data sheet Fig 4f · Fig. 4f source data · Fig. 4f
time to normalized PL maximum	AH: 0.1 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
time to normalized PL maximum	MBA: 8 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
time to normalized PL maximum	NEA: 10 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
time to normalized PL maximum	PA: 2.5 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
time to normalized PL maximum	PDA/BDA label in source data: 3.5 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
time to normalized PL maximum	PEA: 9 days	—	—	SI Table Exact Reported	source-data sheet Fig 4b · Fig. 4b source data · Fig. 4b
room-temperature PLQY range for amine-treated PbI2@MOF	about 1-15%	—	—	Text Range	422 · Physical properties

steady-state photoluminescence

Photoluminescence and fluorescence spectroscopy

S-MBA/PbI2@PCN-609 amine-modified crystals · Single Crystal

S-MBA/PbI2@MOF measured at 78 K; source data Fig. 4f

Temperature: 78
Geometry: single crystal
Context: amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-MBA/PbI2@MOF PL peak wavelength	580 nm at normalized maximum in source data	—	—	SI Table Exact Reported	source-data sheet Fig 4f · Fig. 4f source data · Fig. 4f

steady-state photoluminescence

Photoluminescence and fluorescence spectroscopy

S-MBA/PbI2@PCN-700 amine-modified crystals · Single Crystal

S-MBA/PbI2@MOF measured at 78 K; source data Fig. 4f

Temperature: 78
Geometry: single crystal
Context: amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4f

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
S-MBA/PbI2@MOF PL peak wavelength	477.5 nm at normalized maximum in source data	—	—	SI Table Exact Reported	source-data sheet Fig 4f · Fig. 4f source data · Fig. 4f

ultrafast transient absorption

Transient absorption spectroscopy

PbI2@NU-1000 single crystals · Single Crystal

Pump 320 nm; probe 450-650 nm; sample dispersed in acetonitrile

Temperature: 298
Atmosphere: ambient
Geometry: cuvette
Context: guest-loaded superlattice
Measurement source: 425 · Ultrafast transient absorption spectroscopic characterizations

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average recovery lifetime	132 +- 12 ps	—	+- 12 ps	Text Exact Reported	422 · Physical properties

ultrafast transient absorption

Transient absorption spectroscopy

PbI2@PCN-606 single crystals · Single Crystal

Pump 320 nm; probe 450-650 nm; sample dispersed in acetonitrile

Temperature: 298
Atmosphere: ambient
Geometry: cuvette
Context: guest-loaded superlattice
Measurement source: 425 · Ultrafast transient absorption spectroscopic characterizations

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average recovery lifetimeMarked as a best value within this paper	1619 +- 509 ps	—	+- 509 ps	Text Exact Reported	422 · Physical properties

ultrafast transient absorption

Transient absorption spectroscopy

PbI2@PCN-609 single crystals · Single Crystal

Pump 320 nm; probe 450-650 nm; sample dispersed in acetonitrile

Temperature: 298
Atmosphere: ambient
Geometry: cuvette
Context: guest-loaded superlattice
Measurement source: 425 · Ultrafast transient absorption spectroscopic characterizations

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average recovery lifetime	1317 +- 244 ps	—	+- 244 ps	Text Exact Reported	422 · Physical properties

ultrafast transient absorption

Transient absorption spectroscopy

PbI2@PCN-700 single crystals · Single Crystal

Pump 320 nm; probe 450-650 nm; sample dispersed in acetonitrile

Temperature: 298
Atmosphere: ambient
Geometry: cuvette
Context: guest-loaded superlattice
Measurement source: 425 · Ultrafast transient absorption spectroscopic characterizations

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
average recovery lifetime	368 +- 14 ps	—	+- 14 ps	Text Exact Reported	422 · Physical properties

UV-visible diffuse reflectance / Tauc analysis

UV-visible and optical absorption spectroscopy

S-MBA/PbI2@PCN-606 amine-modified crystals · Single Crystal

solid-state UV-vis; Kubelka-Munk direct bandgap linear fit

Temperature: 298
Geometry: single crystal
Context: amine-modified superlattice
Measurement source: 423 · Fig. 4 caption · Fig. 4d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PbI2@PCN-606 direct bandgap	1.95 eV	—	—	Figure Axis Rounded Reported	423 · Fig. 4d · Fig. 4d
PCN-606 direct bandgap	2.99 eV	—	—	Figure Axis Rounded Reported	423 · Fig. 4d · Fig. 4d
S-MBA/PbI2@PCN-606 direct bandgap	1.75 eV	—	—	Figure Axis Rounded Reported	423 · Fig. 4d · Fig. 4d