Zhang W., Jiang H., Liu Y. et al. · Nature · 2025 · 418-424
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Chiral amine incorporation gives strong circularly polarized luminescence in PbI2@PCN-606, with P near 28-29% at cryogenic temperature.
Caveat: Main CPL values are optical measurements at 77-78 K; room-temperature values are lower in SI temperature series.
423 · Tailoring optical properties · Fig. 4h · Linked to 3 structured results
Higher-dimensional PbI2 sublattices in the 3D MOF framework improve photoexcited carrier lifetime, photocurrent response and charge-transfer resistance.
Caveat: Photocurrent and EIS comparisons are largely graphical/qualitative except for the reported 115 ohm PCN-606 value.
S4-S5 · Physical properties · Linked to 3 structured results
PbI2@MOF superlattices retain permanent porosity after guest loading, with BET areas from 416 to 1083 cm2 g-1 for the four main PbI2@MOFs.
Caveat: Surface areas decrease relative to pristine templates for several samples.
421-422 · Physical properties · Linked to 4 structured results
Coordination between metal-halide guests and unsaturated Zr6-node sites directs nucleation and confined growth into 0D, 1D and 2D superlattices.
Caveat: Mechanistic details are inferred from time-dependent SC-XRD and supporting characterization rather than in situ spectroscopy for every framework.
419 · Confined growth mechanism · Linked to 3 structured results
Amine-modified PbI2@MOF photoluminescence is assigned to exciton emission rather than defect emission.
Caveat: Authors describe the spectroscopy study as preliminary for complex amine/PbI2@MOF structures.
S6-S7 · Physical mechanism of PL emission · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| CdI2@NU-1000 | CdI2 guest in NU-1000Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D CdI2@NU-1000 superlattice | 419 · structural characterization · Supplementary Fig. 4 |
| CdI2@NU-600 | CdI2 guest in NU-600Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Compositehollow quasi-spherical Cd-based cluster in NU-600 | S14 · structural characterization · Supplementary Fig. 5 |
| NiBr2@NU-1000 | NiBr2 guest in NU-1000Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D NiBr2@NU-1000 superlattice | 419 · structural characterization · Supplementary Fig. 3 |
| NiBr2@PCN-700 | NiBr2 guest in PCN-700Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D NiBr2@PCN-700 superlattice | 721 · structural characterization · Extended Data Fig. 3 |
| NU-1000 | Zr6O4(OH)8(H2O)4(L1)2 (reported for PbI2@NU-1000-I parent framework)Zr6 oxo/hydroxo clusters · H4TBAPy-derived pyrene tetracarboxylate linker (L1) | 3D · Pristinezirconium(IV) MOF template with large hexagonal and smaller rhombic channels | S7 · Synthesis of MOF templates |
| NU-600 | Zr MOF based on H4TCPB-Br2 linkerZr6 oxo/hydroxo clusters · H4TCPB-Br2 | 3D · Pristinezirconium(IV) MOF template with cubic cages | S8 · Synthesis of MOF templates |
| NU-600>PbI2 | PbI2 host-guest inclusion in NU-600Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D host-guest superstructure, not stable superlattice | 724 · structural characterization · Extended Data Fig. 6 |
| PbBr2@NU-1000 | PbBr2 guest in NU-1000Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D PbBr2@NU-1000 superlattice | 419 · structural characterization · Extended Data Fig. 1 |
| PbBr2@NU-600 | PbBr2 guest in NU-600Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Compositehollow quasi-spherical PbBr2 cluster in NU-600 | 724 · structural characterization · Extended Data Fig. 2 |
| PbBr2@PCN-606 | PbBr2 guest in PCN-606Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 2D · Compositeanalogous fully filled 2D PbBr2@PCN-606 superlattice | 724 · structural characterization · Extended Data Fig. 5 |
| PbBr2@PCN-700 | PbBr2 guest in PCN-700Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 1D · Compositelateral-1D PbBr2@PCN-700 superlattice | 724 · structural characterization · Extended Data Fig. 4 |
| PbI2@NU-1000 | PbI2 guest in NU-1000Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Composite0D distorted cuboid PbI2 clusters in NU-1000 rhombic nanochannels | S11 · structural characterization · Supplementary Fig. 2 |
| PbI2@NU-600 | PbI2 guest in NU-600Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 0D · Compositehollow quasi-spherical Pb-based cluster in NU-600 | S15 · structural characterization · Supplementary Fig. 6 |
| PbI2@PCN-606 | PbI2 guest in PCN-606Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 2D · Compositefully filled 2D PbI2 layer/superlattice | 420 · structural characterization · Fig. 1 |
| PbI2@PCN-609 | PbI2 guest in PCN-609Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 2D · Compositehalf-filled 2D PbI2 unit/superlattice | 420 · structural characterization · Fig. 1 |
| PbI2@PCN-700 | PbI2 guest in PCN-700Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 1D · Composite1D PbI2 chains/nanorods within PCN-700 channels | 420 · structural characterization · Fig. 1 |
| PCN-606 | Zr MOF based on H4TPCB linkerZr6 oxo/hydroxo clusters · H4TPCB | 3D · Pristineflexible low-symmetry zirconium(IV) MOF with adaptable framework | S8 · Synthesis of MOF templates |
| PCN-609 | Zr MOF based on H4CBTB linkerZr6 oxo/hydroxo clusters · H4CBTB | 3D · Pristinerigid low-symmetry zirconium(IV) MOF with three nanochannels | S8 · Synthesis of MOF templates |
| PCN-700 | Zr MOF based on H2Me2-BPDC linkerZr6 oxo/hydroxo clusters · H2Me2-BPDC | 3D · Pristineflexible zirconium(IV) MOF with tetragonal-like nanochannels | S8 · Synthesis of MOF templates |
| PCN-700>PbI2 | PbI2 host-guest inclusion in PCN-700Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker | 1D · Composite1D host-guest superstructure, decomposes in DMF | 724 · structural characterization · Extended Data Fig. 7 |
| R-MBA/PbI2@PCN-606 | R-MBA-modified PbI2@PCN-606Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 2D · Compositechiral amine-modified PbI2@PCN-606 CPL material | 423 · structural characterization · Fig. 4h |
| S-MBA/PbI2@NU-1000 | S-MBA-modified PbI2@NU-1000Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 0D · Compositeamine-modified perovskite-like PbI2@MOF luminophore | 423 · structural characterization · Fig. 4f |
| S-MBA/PbI2@PCN-606 | S-MBA-modified PbI2@PCN-606Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 2D · Compositeamine-modified perovskite-like PbI2@MOF luminophore | 423 · structural characterization · Fig. 4 |
| S-MBA/PbI2@PCN-609 | S-MBA-modified PbI2@PCN-609Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 2D · Compositeamine-modified perovskite-like PbI2@MOF luminophore | 423 · structural characterization · Fig. 4f |
| S-MBA/PbI2@PCN-700 | S-MBA-modified PbI2@PCN-700Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 1D · Compositeamine-modified perovskite-like PbI2@MOF luminophore | 423 · structural characterization · Fig. 4f |
| S-NEA/PbI2@PCN-606 | S-NEA-modified PbI2@PCN-606Zr6 oxo/hydroxo MOF nodes plus confined metal-halide sublattice · parent MOF linker; amine guest where named | 2D · Compositechiral naphthylamine-modified PbI2@PCN-606 CPL material | 423 · structural characterization · Supplementary Fig. 67 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| CdI2@NU-1000 single crystalsresearch_0463__mat__m_cdi2_nu1000 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| CdI2@NU-600 single crystalsresearch_0463__mat__m_cdi2_nu600 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| NiBr2@NU-1000 single crystalsresearch_0463__mat__m_nibr2_nu1000 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| NiBr2@PCN-700 single crystalsresearch_0463__mat__m_nibr2_pcn700 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| NU-1000 single crystalsresearch_0463__mat__m_nu1000 | Single Crystal · Pristine Control · Pristine Framework | washed/activated MOF template | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| NU-600 single crystalsresearch_0463__mat__m_nu600 | Single Crystal · Pristine Control · Pristine Framework | washed/activated MOF template | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| NU-600>PbI2 host-guest crystalsresearch_0463__mat__m_nu600_pbi2_hostguest | Single Crystal · Target Sample · Guest Loaded | host-guest growth, decomposes in DMF | 724 · Extended Data · Extended Data Fig. 6 |
| PbBr2@NU-1000 single crystalsresearch_0463__mat__m_pbbr2_nu1000 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbBr2@NU-600 single crystalsresearch_0463__mat__m_pbbr2_nu600 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbBr2@PCN-606 single crystalsresearch_0463__mat__m_pbbr2_pcn606 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbBr2@PCN-700 single crystalsresearch_0463__mat__m_pbbr2_pcn700 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| template-free rodlike PbI2 nanorodsresearch_0463__mat__m_pbi2_pcn700 | Single Crystal · Model System · Model | template-free comparison | S8 · Synthesis of rodlike PbI2 crystal |
| PbI2@NU-1000 single crystalsresearch_0463__mat__m_pbi2_nu1000 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbI2@NU-600 single crystalsresearch_0463__mat__m_pbi2_nu600 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbI2@PCN-606 single crystalsresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbI2@PCN-606-I intermediateresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | time-dependent intermediate in confined growth | 419 · Confined growth mechanism · Fig. 2 |
| PbI2@PCN-606-II intermediateresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | time-dependent intermediate in confined growth | 419 · Confined growth mechanism · Fig. 2 |
| PbI2@PCN-606-III intermediateresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | time-dependent intermediate in confined growth | 419 · Confined growth mechanism · Fig. 2 |
| PbI2@PCN-606-IV intermediateresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | time-dependent intermediate in confined growth | 419 · Confined growth mechanism · Fig. 2 |
| PbI2@PCN-606-V intermediateresearch_0463__mat__m_pbi2_pcn606 | Single Crystal · Target Sample · Guest Loaded | time-dependent intermediate in confined growth | 419 · Confined growth mechanism · Fig. 2 |
| PbI2@PCN-609 single crystalsresearch_0463__mat__m_pbi2_pcn609 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PbI2@PCN-700 single crystalsresearch_0463__mat__m_pbi2_pcn700 | Single Crystal · Target Sample · Guest Loaded | confined growth in MOF pores | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PCN-606 single crystalsresearch_0463__mat__m_pcn606 | Single Crystal · Pristine Control · Pristine Framework | washed/activated MOF template | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PCN-609 single crystalsresearch_0463__mat__m_pcn609 | Single Crystal · Pristine Control · Pristine Framework | washed/activated MOF template | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PCN-700 single crystalsresearch_0463__mat__m_pcn700 | Single Crystal · Pristine Control · Pristine Framework | washed/activated MOF template | 419 · Synthesis and X-ray crystal structures · Fig. 1 |
| PCN-700>PbI2 host-guest crystalsresearch_0463__mat__m_pcn700_pbi2_hostguest | Single Crystal · Target Sample · Guest Loaded | host-guest growth, decomposes in DMF | 724 · Extended Data · Extended Data Fig. 7 |
| R-MBA/PbI2@PCN-606 amine-modified crystalsresearch_0463__mat__m_rmba_pbi2_pcn606 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |
| S-MBA/PbI2@NU-1000 amine-modified crystalsresearch_0463__mat__m_smba_pbi2_nu1000 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |
| S-MBA/PbI2@PCN-606 amine-modified crystalsresearch_0463__mat__m_smba_pbi2_pcn606 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |
| S-MBA/PbI2@PCN-609 amine-modified crystalsresearch_0463__mat__m_smba_pbi2_pcn609 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |
| S-MBA/PbI2@PCN-700 amine-modified crystalsresearch_0463__mat__m_smba_pbi2_pcn700 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |
| S-NEA/PbI2@PCN-606 amine-modified crystalsresearch_0463__mat__m_snea_pbi2_pcn606 | Single Crystal · Target Sample · Composite | amine diffusion modification of PbI2@MOF crystals | 423 · Tailoring optical properties · Fig. 4 |