Metal-halide porous framework superlattices
Zhang W., Jiang H., Liu Y. et al. · Nature · 2025
Reported here: NU-1000
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7 papers
Zhang W., Jiang H., Liu Y. et al. · Nature · 2025
Reported here: NU-1000
Yan M., Bowman Z., Knepp Z.J. et al. · Journal of Physical Chemistry Letters · 2024
Reported here: NU-1000
Li X., Surendran Rajasree S., Gude V. et al. · Angewandte Chemie - International Edition · 2023
Reported here: NU-1000
Noh H., Yang Y., Zhang X. et al. · ChemElectroChem · 2020
Reported here: NU-1000
Goswami S., Hod I., Duan J.D. et al. · Journal of the American Chemical Society · 2019
Reported here: NU-1000
Kung C.-W., Otake K., Buru C.T. et al. · Journal of the American Chemical Society · 2018
Reported here: NU-1000
Hod I., Deria P., Bury W. et al. · Nature Communications · 2015
Reported here: NU-1000
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| NU-10002025 · Metal-halide porous framework superlattices | Zr6O4(OH)8(H2O)4(L1)2 (reported for PbI2@NU-1000-I parent framework)Zr6 oxo/hydroxo clusters · H4TBAPy-derived pyrene tetracarboxylate linker (L1) | 3D · Pristinezirconium(IV) MOF template with large hexagonal and smaller rhombic channels | S7 · Synthesis of MOF templates |
| NU-10002024 · Reaction-Type-Dependent Behavior of Redox-Hopping in MOFs─Does Charge Transport Have a Preferred Direction? | Zr-based NU-1000 MOF; molar mass used in SI model = 2180 g/molZr oxo-metal nodes · 1,3,6,8-tetrakis(p-benzoate)pyrene (H4TBAPy/TBAPy) | 3D · PristinePorous NU-1000 scaffold with hexagonal tunnels; PXRD of NU-1000 and Ru-NU-1000 compared with simulated NU-1000. | p002 / article page 11920 · Results and discussion · Figure 2 |
| NU-10002023 · Decoupling Redox Hopping and Catalysis in Metal-Organic Frameworks -based Electrocatalytic CO2 Reduction | Not specifiedZr(IV)6-oxo secondary building units · carboxy-terminated tetraphenylpyrene, TBAPy | 3D · PristineHydrolytically stable pyrene-based zirconium MOF with 1D mesopore channels along the c axis. | 1 · Introduction |
| NU-10002020 · Single-Site, Single-Metal-Atom, Heterogeneous Electrocatalyst: Metal–Organic-Framework Supported Molybdenum Sulfide for Redox Mediator-Assisted Hydrogen Evolution Reaction | Zr6 oxozirconium node with TBAPy linkerhexanuclear oxozirconium-based Zr6 node · 1,3,5,8-(p-benzoate)pyrene linker (TBAPy4-) | 3D · PristineHierarchical microporous and mesoporous Zr-MOF support with labile hydroxo/aqua groups on nodes. | 510 · Introduction · Figure 1 |
| NU-10002019 · Anisotropic Redox Conductivity within a Metal-Organic Framework Material | Zr6-based NU-1000 with TPPy(COO-)4 linkersRedox-inert hexazirconium(IV) oxy clusters; oxy-Zr6 cluster. · Carboxy-terminated tetraphenylpyrene linker, TPPy(COO-)4, from H4TBAPy. | 3D · Pristinecsq topology with one-dimensional hexagonal and trigonal mesopores/channels; rod-like hexagonal crystallites. | 1-2 · Abstract; Introduction · Figure 1 |
| NU-10002018 · Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests | Not specifiedHexa-zirconium nodes · Pyrene-based TBAPy linkers, 1,3,6,8-tetrakis(p-benzoic acid)pyrene-derived | 3D · PristineMesoporous zirconium-based MOF with one-dimensional mesoporous hexagonal channels and microporous triangular channels. | 3871 · introduction |
| NU-10002015 · A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution | Zr6(mu3-O)4(mu3-OH)4(OH)4(OH2)4 with TBAPy4- linkersHexa-zirconium oxo/hydroxo/aquo Zr6 nodes bearing terminal OH and OH2 ligands · 1,3,6,8-tetrakis(p-benzoate)pyrene (TBAPy4-) | 3D · PristineMesoporous NU-1000 framework with triangular and hexagonal one-dimensional channels; acid-stable Zr6-based MOF scaffold. | 2-3 · Results - Electrocatalyst synthesis · Figure 1 |