Electrochemistry Application — Anisotropic Redox Conductivity within a Metal-Organic Framework Material

Measurement evidence

Electrochemistry Application

Anisotropic Redox Conductivity within a Metal-Organic Framework Material · Goswami S., Hod I., Duan J.D. et al. · Journal of the American Chemical Society · 2019 · 17696-17702

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

EPD NU-1000 thin film on ZnO-coated FTO · Electrode

1 M TBAPF6 in CH2Cl2/DCM; scan rate 100 mV s-1; Ag/AgCl/KCl reference; Pt mesh counter electrode.

Geometry
three-electrode cell with NU-1000 thin-film/FTO working electrode
Context
pristine NU-1000 thin film on FTO/ZnO
Measurement source
3 · Results and Discussion · Figure 5B
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
EPD-film CV evidence of slower transportPeak separation and tailing of voltammetric waves are more prominent for EPD-prepared films, implying slower charge transport.Text
Qualitative
3 · Results and Discussion · Figure 5A-B

Cyclic voltammetry

Solvothermal NU-1000 thin film on ZnO-coated FTO · Electrode

1 M TBAPF6 in CH2Cl2/DCM; scan rate 100 mV s-1; Ag/AgCl/KCl reference; Pt mesh counter electrode.

Geometry
three-electrode cell with NU-1000 thin-film/FTO working electrode
Context
pristine NU-1000 thin film on FTO/ZnO
Measurement source
3 · Results and Discussion · Figure 5A
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Solvothermal-film TPPy redox peaksCV shows peaks attributable to the MOF-based TPPy+/0 couple.Text
Qualitative
3 · Results and Discussion · Figure 5A