Diffraction Structure — Anisotropic Redox Conductivity within a Metal-Organic Framework Material

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

NU-1000 TPPy linker-pair coupling model · Model

Distances and channel sizes used to interpret redox hopping and charge-compensating ion motion.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BARF anion diameter	15 Angstrom	—	—	Text Rounded Reported	4 · Results and Discussion
NU-1000 hexagonal channel width	about 30 Angstrom	—	about	Text Approximate	4 · Results and Discussion
a,b-plane effective hopping distance	2.6 nm	—	about	Text Approximate	8 · Figure S6 discussion · Figure S6
c-direction TPPy hopping distance	1.6 nm	—	about	Text Approximate	2 · Results and Discussion · Figure 1
PF6 anion diameter	5 Angstrom	—	—	Text Rounded Reported	4 · Results and Discussion
NU-1000 trigonal channel width	about 12 Angstrom	—	about	Text Approximate	4 · Results and Discussion

EPD NU-1000 thin film on ZnO-coated FTO · Electrode

Room-temperature PXRD on EPD film; comparison to simulated NU-1000 pattern.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
NU-1000 (001) PXRD peak position	peak at 2theta = 5.2 degrees	—	—	Caption Rounded Reported	5 · Figure S2 caption · Figure S2
EPD film preferred orientation	(001) planes preferentially oriented parallel to the FTO substrate; simulated pattern with r < 1.	—	—	Text Qualitative	3 · Results and Discussion · Figure S2

Solvothermal NU-1000 thin film on ZnO-coated FTO · Electrode

Room-temperature PXRD on as-grown film; Cu X-ray tube at 40 kV and 40 mA; 1.5 to 21 degrees two theta over 30 min.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Solvothermal film preferred orientation	(001) planes preferentially oriented perpendicular to the FTO substrate; simulated pattern with r > 1.	—	—	Text Qualitative	3 · Results and Discussion · Figure S2
PXRD phase match for solvothermal film	Observed PXRD patterns are in accordance with the simulated powder XRD pattern of NU-1000.	—	—	Text Qualitative	2 · Results and Discussion · Figure S2