Spectroscopy — Efficient MOF-Sensitized Solar Cells Featuring Solvothermally Grown [100]-Oriented Pillared Porphyrin Framework-11 Films on ZnO/FTO Surfaces

6 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

C60-doped PPF-11 crystals · Powder

Known C60-doped PPF-11 soaked in hot toluene; washes analysed by Lambert-Beer law

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PPF-11 cavity occupancy by C60	roughly half of cavities occupied	—	—	Calculated From Reported Approximate	3200 · Doping PPF-11 with C60
encapsulated C60 mass	2.9 mg C60 in 9.5 mg C60-doped PPF-11	—	—	Text Rounded Reported	3200 · Doping PPF-11 with C60
C60 LUMO level	-4.2 eV	—	—	Text Rounded Reported	3200 · Doping PPF-11 with C60
ZnTCPP/C60 ratio	2:1	—	—	Calculated From Reported Approximate	3200 · Doping PPF-11 with C60
C60-doped PPF-11 mass for extraction	9.5 mg	—	—	Text Rounded Reported	3200 · Doping PPF-11 with C60

[100]-oriented PPF-11 film on TCPP-coated ZnO-FTO · Electrode

300 MHz; one drop CF3CO2D in DMSO-d6; compares scraped film and bulk crystals

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TCPP:DMBPY ligand ratio	1:1	—	—	Text Exact Reported	3199 · Spontaneous solvothermal growth · Figure S1

C60-doped PPF-11 crystals · Powder

Comparison of PPF-11, C60-doped PPF-11, and free ZnTCPP

Context: guest-loaded emission quenching
Measurement source: 3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3b

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
photoluminescence quenching	PL diminished significantly from undoped PPF-11	—	—	Qualitative Qualitative	3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3b

[100]-oriented PPF-11 film on TCPP-coated ZnO-FTO · Electrode

Excitation at 432 nm

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PL amplification versus free ZnTCPP	ca. 10^3 times higher	—	—	Text Approximate	3200 · Optical Properties of PPF-11 · Figure 3b
PPF-11 emission peak	610 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3b
PPF-11 emission peak	660 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3b

C60-doped PPF-11 crystals · Powder

Shimadzu UV-2600 integrated sphere; undoped and C60-doped PPF-11

Context: guest-loaded optical CT
Measurement source: 3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3a inset

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
C60-doped PPF-11 CT band high end	930 nm	—	—	Text Rounded Reported	3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3a inset
C60-doped PPF-11 CT band low end	650 nm	—	—	Text Rounded Reported	3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3a inset
C60-doped PPF-11 optical band gap	1.3 eV	—	—	Text Rounded Reported	3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3a inset
band-gap narrowing versus undoped PPF-11	about 0.6 eV narrower	—	—	Calculated From Reported Approximate	3201 · Optical and Electronic Properties of C60-Doped PPF-11 · Figure 3a inset

[100]-oriented PPF-11 film on TCPP-coated ZnO-FTO · Electrode

Shimadzu UV-2600; solid films

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
longest wavelength absorption onset	670 nm	—	—	Text Rounded Reported	3200 · Optical Properties of PPF-11 · Figure 3a
optical band gap	about 1.9 eV from 670 nm onset	—	—	Text Approximate	3200 · Optical Properties of PPF-11 · Figure 3a
Q band	566 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3a
Q band	607 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3a
Q band	650 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3a
Soret band	430 nm	—	—	Text Exact Reported	3200 · Optical Properties of PPF-11 · Figure 3a