Gordillo M.A., Panda D.K., Saha S. · ACS Applied Materials and Interfaces · 2019 · 3196-3206
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
EQE profiles resemble porphyrin absorption, supporting that ZnTCPP ligands in PPF-11 produce the photocurrent.
Caveat: EQE peak values were read approximately from the plotted axis.
3202 · Photovoltaic Performance · Linked to 5 structured results
The best reported replicate for [100]-oriented PPF-11/ZnO-FTO reaches Jsc 4.65 mA/cm2, Voc 469 mV, FF 39%, and PCE 0.86% under 1 sun.
Caveat: Main Table 1 average is lower PCE 0.82 +/- 0.05%; best single replicate is from SI Table S1.
S-6 · Table S1 · Table S1 · Linked to 4 structured results
Although related host-guest CT interactions can enhance conductivity, C60-doped PPF-11/ZnO films showed no measurable conductivity surge in this paper.
Caveat: The supplied text does not give the conductivity measurement method or numeric detection limit.
3198 · Results and Discussion · Linked to 1 structured result
C60 guests create ZnTCPP/C60 charge-transfer absorption and PL quenching but weaken photovoltaic response relative to pristine PPF-11 films.
Caveat: Mechanism is inferred from electrolyte exclusion and isolated C60 guests rather than directly imaged transport paths.
3203 · Conclusions · Linked to 5 structured results
The [100]-oriented, covalently attached PPF-11/ZnO photoanode gives higher Jsc/PCE and lower R2 than drop-cast [001]-oriented controls.
Caveat: Authors state individual contributions cannot be fully separated experimentally.
3203 · Conclusions · Linked to 5 structured results
ZnO-bound TCPP ligands capture porphyrin struts and guide [100]-oriented PPF-11 film growth directly on ZnO-FTO without insulating SAMs.
Caveat: Main text notes both bare and TCPP-precoated ZnO yield [100] films; TCPP precoat improves uniformity/robustness.
3199 · Spontaneous solvothermal growth · Linked to 2 structured results
Lower photoanode/electrolyte charge-transfer resistance R2 correlates with stronger photovoltaic performance across the devices.
Caveat: EIS is application-device transport, not intrinsic MOF conductivity.
3203 · Photovoltaic Performance · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| C60-doped PPF-11 | C60@ [Zn2(ZnTCPP)(DMBPY)]; estimated ZnTCPP/C60 = 2:1PPF-11 Zn2(COO)4 paddle-wheel nodes retained after C60 infiltration · ZnTCPP and DMBPY framework with encapsulated C60 guests | 3D · CompositeGuest-loaded noncatenated PPF-11; PXRD mostly unchanged after C60 infiltration with some new peaks. | 3200 · Doping PPF-11 with electron-accepting C60 guests |
| Pillared porphyrin framework-11 (PPF-11) | [Zn2(ZnTCPP)(DMBPY)]Zn2(COO)4 paddle-wheel nodes with ZnTCPP struts; DMBPY axially coordinates Zn2 nodes · Zn-tetrakis(4-carboxyphenyl)porphyrin (ZnTCPP) and 2,2-dimethyl-4,4-bipyridine (DMBPY) | 3D · PristineNoncatenated pillared porphyrin framework with AA stacking and large cavities; bulk preferential [001], solvothermal ZnO film [100]. | 3198 · Bulk PPF-11 synthesis and characterization · Figure 1 |
| TCPP-coated ZnO-FTO control electrode | TCPP monolayer on ZnO-FTOZnO surface anchors carboxylate groups · meso-tetrakis(4-carboxyphenyl)porphyrin (TCPP) | unknown · CompositeMolecular porphyrin-coated ZnO-FTO control and growth-directing substrate. | S-5 · Solvothermal Growth |
| ZnO-FTO control electrode | ZnO on FTO glass | unknown · Model SystemAnnealed semiconducting ZnO film on FTO; non-MOF control and growth substrate. | S-4 · Preparation of ZnO films |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| C60-doped [100]-oriented PPF-11/ZnO-FTO filmresearch_0630__mat__mat_c60_ppf11 | Electrode · Target Sample · Guest Loaded | PPF-11/ZnO film solvent-exchanged to toluene, C60-loaded, washed with fresh tolueneTCPP-coated annealed ZnO-FTO · ca. 10 um before doping | S-4 · Doping PPF-11 with C60 |
| C60-doped PPF-11 crystalsresearch_0630__mat__mat_c60_ppf11 | Powder · Target Sample · Guest Loaded | solvent-exchanged to toluene, soaked in saturated C60/toluene, washed; dark violet | S-4 · Doping PPF-11 with C60 |
| drop-cast PPF-11 on TCPP/ZnO-FTOresearch_0630__mat__mat_ppf11 | Electrode · Pristine Control · Composite | 10 drops of PPF-11 suspension in CHCl3 deposited sequentially; predominantly [001] orientationTCPP-coated ZnO-FTO | S-5 · Drop-Cast PPF-11 Films |
| drop-cast PPF-11 on ZnO-FTOresearch_0630__mat__mat_ppf11 | Electrode · Pristine Control · Composite | PPF-11 suspension in CHCl3 drop-cast onto annealed ZnO-FTObare ZnO-FTO | S-5 · Drop-Cast PPF-11 Films |
| [100]-oriented PPF-11 film on unmodified ZnO-FTOresearch_0630__mat__mat_ppf11 | Thin Film · Pristine Control · Pristine Framework | solvothermally grown directly on unmodified ZnO; identical PXRD orientation to TCPP-precoated filmsbare annealed ZnO-FTO | 3199 · Spontaneous solvothermal growth |
| [100]-oriented PPF-11 film on TCPP-coated ZnO-FTOresearch_0630__mat__mat_ppf11 | Electrode · Target Sample · Pristine Framework | solvothermally grown 30 min; washed/soaked in DMF; covalently attached through TCPP/ZnO interfaceTCPP-precoated annealed ZnO-FTO · ca. 10 um PPF-11 layer on 2.5 um ZnO | 3201 · Photovoltaic performance |
| bulk PPF-11 crystalsresearch_0630__mat__mat_ppf11 | Single Crystal · Pristine Control · Pristine Framework | reddish-purple rectangular plate-like crystals washed with DMF and stored in DMF | 3198 · Bulk PPF-11 synthesis and characterization |
| TCPP/ZnO-FTO filmresearch_0630__mat__mat_tcpp_zno_control | Electrode · Pristine Control · Composite | ZnO-FTO soaked in TCPP/EtOH to form TCPP-coated ZnO; no PPF-11 growth in control deviceannealed ZnO-FTO · 2.5 um ZnO layer | 3199 · Spontaneous solvothermal growth |
| blank ZnO-FTO filmresearch_0630__mat__mat_zno_fto_control | Electrode · Pristine Control · Model | ZnO/EtOH spin-coated on FTO and annealed at 350 CFTO glass · 2.5 um ZnO layer | S-4 · Preparation of ZnO films |