Electrochemistry Application — Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes

2 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

receptor 2 in solution · Unknown

Ar-saturated CH2Cl2 with 0.1 M NBu4PF6, Ag/Ag+ reference, Pt counter, glassy carbon working electrode; Fc/Fc+ internal standard; scan rate 0.01 V/s.

Temperature: 298
Atmosphere: Ar-saturated
Geometry: Three-electrode solution cell
Context: receptor 2
Measurement source: S27 · Electrochemical and spectroelectrochemical data · Figure S26

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Approximate anodic DPV peak for receptor 2	+0.10 V vs Fc/Fc+ from labelled Figure S26 trace	—	figure label assignment	Figure Axis Rounded Reported	S27 · Electrochemical data · Figure S26
Approximate cathodic DPV peak for receptor 2	-1.28 V vs Fc/Fc+ from labelled Figure S26 trace	—	figure label assignment	Figure Axis Rounded Reported	S27 · Electrochemical data · Figure S26

receptor 2 in solution · Unknown

Benzonitrile, NBu4PF6 supporting electrolyte; voltage stepped from +0.0 to +1.0 V.

Temperature: 298
Atmosphere: Ar-saturated
Geometry: Three-electrode spectroelectrochemical cell with Pt mesh working electrode, Ag/Ag+ reference and Pt counter
Context: receptor 2
Measurement source: p004-p005 / article pp.11500-11501 · Photophysical Studies · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Spectroelectrochemical feature highlighted in Figure 3a	667 nm	—	from figure label	Figure Axis Rounded Reported	p005 / article p.11501 · Figure 3 · Figure 3a
Spectroelectrochemical voltage range	+0.0 to +1.0 V	—	—	Text Exact Reported	p004 / article p.11500 · Photophysical Studies · Figure 3a