Electrical Transport — Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes

Measurement evidence

Electrical Transport

Semiconducting Supramolecular Organic Frameworks Assembled from a Near-Infrared Fluorescent Macrocyclic Probe and Fullerenes · Kaur R., Sen S., Larsen M.C. et al. · Journal of the American Chemical Society · 2020 · 11497-11505

4 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Two-contact wire-paste single-crystal conductivity

single crystals of pristine receptor 2 · Single Crystal

Voltage swept between -0.2 and 0.2 V at ambient conditions, 40-60% relative humidity, dark, along crystallographic z axis.

Temperature
298
Atmosphere
ambient
Geometry
Wire-paste two-contact probe along crystallographic z axis
Context
pristine control
Measurement source
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical conductivity along z axissigma = 5.9 x 10^-11 S cm^-1 at 298 K5.9e-11 S cm^-1Text
Exact Reported
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5

Two-contact wire-paste single-crystal conductivity

single crystals of (2*C60)n SOF · Single Crystal

Voltage swept between -0.2 and 0.2 V at ambient conditions, 40-60% relative humidity, dark, along crystallographic z axis.

Temperature
298
Atmosphere
ambient
Geometry
Wire-paste two-contact probe along crystallographic z axis
Context
C60-loaded SOF
Measurement source
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical conductivity along z axissigma = 1.8 x 10^-10 S cm^-11.8e-10 S cm^-1Text
Exact Reported
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5

Two-contact wire-paste single-crystal conductivity

single crystals of (2*C70)n SOF · Single Crystal

Voltage swept between -0.2 and 0.2 V at ambient conditions, 40-60% relative humidity, dark, along crystallographic z axis.

Temperature
298
Atmosphere
ambient
Geometry
Wire-paste two-contact probe along crystallographic z axis
Context
C70-loaded SOF
Measurement source
S45-S48 · Single crystal conductivity experiments · Figures S57-S61
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Electrical conductivity along z axisMarked as a best value within this paper1.3 x 10^-8 S cm^-1 at 298 K1.3e-8 S cm^-1Text
Exact Reported
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5
Approximate average C70 SOF conductivity from Figure 5bapproximately 2-3 x 10^-9 S cm^-1 from left C70 bar in Figure 5b2.5e-9 S cm^-1visual estimate from logarithmic bar chartVisual Estimate
Approximate
p007 / article p.11503 · Figure 5 caption · Figure 5b
Perpendicular-axis conductivityevidence of lower conductivity, but no reliable conductivity values derivedQualitative
Qualitative
p006 / article p.11502 · Single-Crystal Conductivity Studies · Figure 5; Figure S58

Photoinduced single-crystal conductivity under monochromatic and white-light illumination

single crystals of (2*C70)n SOF · Single Crystal

Crystalline samples exposed to 400, 500, 600 nm and 500-1000 nm white light 10 s prior to and during conductivity measurements.

Temperature
298
Atmosphere
ambient
Geometry
Wire-paste two-contact probe
Context
2, (2*C60)n and (2*C70)n
Measurement source
S46-S48 · Single crystal conductivity experiments · Figures S60-S61
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Photoinduced conductivity responseno observable changes in conductivities under 400, 500, 600 nm or white lightQualitative
Qualitative
S46 · Single crystal conductivity experiments · Figures S60-S61