cMOF Evidence Base
Spectroscopy — Fibrous Pb(II)-Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High-Rate, Selective CO2-to-Formate Conversion

Measurement evidence

Spectroscopy

Fibrous Pb(II)-Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High-Rate, Selective CO2-to-Formate Conversion · Suppaso C., Nakazato R., Nakahata S. et al. · Advanced Functional Materials · 2025 · 2417223

2 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

UV-vis-NIR diffuse-reflectance spectroscopy

UV-visible and optical absorption spectroscopy

MW_x KGF-9/KGF-17 comparison powder series · Powder

Diffuse-reflectance spectra for ordinary KGF-9, KGF-17 and MW_x samples.

Context
Pristine and mixed CP powder optical absorption.
Measurement source
3 · 2.1 Physicochemical Properties · Figure 1B
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Absorption edge of KGF-17480 nm——Text
Rounded Reported		2 · 2.1 Physicochemical Properties · Figure 1B
Absorption edge of KGF-9Marked as a best value within this paper510 nm——Text
Rounded Reported		2 · 2.1 Physicochemical Properties · Figure 1B
Bandgap energies of KGF-9 samplesca. 2.45 +/- 0.03 eV—+/- 0.03 eVText
Approximate		3 · 2.1 Physicochemical Properties · Figure 1B

X-ray photoelectron spectroscopy (XPS), C 1s 285.0 eV reference

X-ray photoelectron spectroscopy

MW_x KGF-9/KGF-17 comparison powder series · Powder

Surface atomic S/Pb and N/Pb ratios for ordinary KGF-9 and MW-treated samples.

Context
Surface composition of pristine and MW-derived KGF-9 powders.
Measurement source
S-2 · Supporting Information · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
N/Pb ratio after longer MW treatment1.9——Text
Exact Reported		3 · 2.1 Physicochemical Properties · Table S3
120 min N/Pb surface atomic ratio1.9——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
60 min N/Pb surface atomic ratio2.2——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
90 min N/Pb surface atomic ratio2.1——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
0 min (Ordinary KGF-9) N/Pb surface atomic ratio2.2——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
S/Pb ratio after longer MW treatment2.7——Text
Exact Reported		3 · 2.1 Physicochemical Properties · Table S3
120 min S/Pb surface atomic ratio2.7——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
60 min S/Pb surface atomic ratio3.1——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
90 min S/Pb surface atomic ratio2.8——SI Table
Exact Reported		S-2 · Supporting Information · Table S3
0 min (Ordinary KGF-9) S/Pb surface atomic ratio3.3——SI Table
Exact Reported		S-2 · Supporting Information · Table S3