Other — Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework

Measurement evidence

Other

Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework · Snook K.M., Zasada L.B., Chehada D. et al. · Chemical Science · 2022 · 10472-10478

10 measurement groups · 34 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Dynamic light scattering

Dynamic light scattering and zeta potential

Acros HHTP batch 2 · Model

1:1 DMSO/H2O; samples sonicated >=30 min before analysis; number particle size distribution.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DLS number PSD diameter mode	160 +/- 40 nm	—	+/- 40 nm	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number fraction for diameter mode	84%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number PSD diameter mode	790 +/- 270 nm	—	+/- 270 nm	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number fraction for diameter mode	16%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S2

Dynamic light scattering

Dynamic light scattering and zeta potential

Purified HHTP plus 0.3 equiv 2,5-dichloro-1,4-benzoquinone · Model

1:1 DMSO/H2O; samples sonicated >=30 min before analysis; number particle size distribution.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DLS number PSD diameter mode	80 +/- 10 nm	—	+/- 10 nm	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number fraction for diameter mode	98%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number PSD diameter mode	530 +/- 130 nm	—	+/- 130 nm	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number fraction for diameter mode	2%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S2

Dynamic light scattering

Dynamic light scattering and zeta potential

TCI HHTP batch 2 · Model

1:1 DMSO/H2O; samples sonicated >=30 min before analysis; number particle size distribution.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
DLS number PSD diameter mode	380 +/- 50 nm	—	+/- 50 nm	SI Table Exact Reported	S11 · Supplementary Tables · Table S2
DLS number fraction for diameter mode	100%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S2

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

Acros HHTP batch 1 · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP content	59.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
water content	2.5 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
unaccounted impurity content	38.5 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

Acros HHTP batch 2 · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP content	68.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
water content	2.5 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
unaccounted impurity content	29.5 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

Purified HHTP · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP contentMarked as a best value within this paper	100.7 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

Purified HHTP plus 0.3 equiv 2,5-dichloro-1,4-benzoquinone · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP content	67.4 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
water content	6.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
unaccounted impurity content	26.6 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

TCI HHTP batch 1 · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP content	87.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
water content	6.7 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
unaccounted impurity content	6.3 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

Quantitative 1H NMR and TGA purity analysis

Nuclear magnetic resonance Thermogravimetric analysis

TCI HHTP batch 2 · Model

HHTP wt% by quantitative NMR; water wt% by TGA where applicable.

Context: linker model
Measurement source: S11 · Supplementary Tables · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
HHTP content	81.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
water content	6.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1
unaccounted impurity content	13.0 wt%	—	—	SI Table Exact Reported	S11 · Supplementary Tables · Table S1

UV-Vis aided quinone sublimation study

UV-visible and optical absorption spectroscopy

Purified HHTP · Model

20 mL vial with quinone and inner 4 mL DMF vial heated at 80 deg C; sublimed quinone measured by UV-Vis.

Temperature: 353
Atmosphere: inert atmosphere box
Context: linker/oxidant model
Measurement source: S12; S21 · Supplementary Tables/Figures · Table S3; Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
1,4-benzoquinone one-electron reduction potential	-0.882 V vs Fc0/+	—	—	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
1,4-benzoquinone sublimation rate	9.7 +/- 3.9 x 10^-4 mmol/min	—	+/- 3.9 x 10^-4 mmol/min	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2-methyl-1,4-benzoquinone one-electron reduction potential	-0.963 V vs Fc0/+	—	—	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2-methyl-1,4-benzoquinone sublimation rate	7.3 +/- 2.5 x 10^-4 mmol/min	—	+/- 2.5 x 10^-4 mmol/min	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2,6-dimethyl-1,4-benzoquinone one-electron reduction potential	-1.035 V vs Fc0/+	—	—	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2,6-dimethyl-1,4-benzoquinone sublimation rate	1.6 +/- 0.2 x 10^-4 mmol/min	—	+/- 0.2 x 10^-4 mmol/min	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2,5-dichloro-1,4-benzoquinone one-electron reduction potential	-0.561 V vs Fc0/+	—	—	SI Table Exact Reported	S12 · Supplementary Tables · Table S3
2,5-dichloro-1,4-benzoquinone sublimation rate	not observed	—	—	SI Table Qualitative	S12 · Supplementary Tables · Table S3