Electrical Transport — Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal-organic framework

5 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HHTP)2 air-synthesis particles · Powder

Packed pellets in PEEK 2-electrode screw cell; 7-10 mg powder; 0.56 Nm torque; settled before current scan.

Atmosphere: not specified
Geometry: packed pellet screw cell
Context: pristine framework pellet
Measurement source: S9; S15 · Electrochemical characterization; Supplementary Tables · Table S7; Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet conductivity replicate 1	2e-02 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 2	3e-02 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 3	9e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
mean pellet conductivity (calculated)Marked as a best value within this paper	0.0197 S/cm	—	—	Calculated From Reported Approximate	S15 · Supplementary Tables · Table S7

Cu3(HHTP)2 air-synthesis rods · Powder

Packed pellets in PEEK 2-electrode screw cell; 7-10 mg powder; 0.56 Nm torque; settled before current scan.

Atmosphere: not specified
Geometry: packed pellet screw cell
Context: pristine framework pellet
Measurement source: S9; S15 · Electrochemical characterization; Supplementary Tables · Table S7; Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet conductivity replicate 1	9e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 2	8e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 3	2e-02 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
mean pellet conductivity (calculated)	0.0123 S/cm	—	—	Calculated From Reported Approximate	S15 · Supplementary Tables · Table S7

Cu3(HHTP)2 blocks, 0.3 equiv 2,5-dichloro pre-oxidant · Powder

Packed pellets in PEEK 2-electrode screw cell; 7-10 mg powder; 0.56 Nm torque; settled before current scan.

Atmosphere: not specified
Geometry: packed pellet screw cell
Context: pristine framework pellet
Measurement source: S9; S15 · Electrochemical characterization; Supplementary Tables · Table S7; Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet conductivity replicate 1	1e-02 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 2	1e-02 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 3	7e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
mean pellet conductivity (calculated)	0.009 S/cm	—	—	Calculated From Reported Approximate	S15 · Supplementary Tables · Table S7

Cu3(HHTP)2 flakes, 0.5 equiv 2,5-dichloro pre-oxidant · Powder

Packed pellets in PEEK 2-electrode screw cell; 7-10 mg powder; 0.56 Nm torque; settled before current scan.

Atmosphere: not specified
Geometry: packed pellet screw cell
Context: pristine framework pellet
Measurement source: S9; S15 · Electrochemical characterization; Supplementary Tables · Table S7; Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet conductivity replicate 1	1e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 2	4e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 3	4e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
mean pellet conductivity (calculated)	0.003 S/cm	—	—	Calculated From Reported Approximate	S15 · Supplementary Tables · Table S7

Cu3(HHTP)2 rods, 0 equiv pre-oxidant · Powder

Packed pellets in PEEK 2-electrode screw cell; 7-10 mg powder; 0.56 Nm torque; settled before current scan.

Atmosphere: not specified
Geometry: packed pellet screw cell
Context: pristine framework pellet
Measurement source: S9; S15 · Electrochemical characterization; Supplementary Tables · Table S7; Figure S20

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
pellet conductivity replicate 1	4e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 2	1e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
pellet conductivity replicate 3	3e-03 S/cm	—	—	SI Table Rounded Reported	S15 · Supplementary Tables · Table S7
mean pellet conductivity (calculated)	0.00267 S/cm	—	—	Calculated From Reported Approximate	S15 · Supplementary Tables · Table S7