Spectroscopy — Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity

Measurement evidence

Spectroscopy

Cation-exchanged conductive Mn2DSBDC metal–organic frameworks: Synthesis, structure, and THz conductivity · Pattengale B., Neu J., Tada A. et al. · Polyhedron · 2021 · 115182

7 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

diffuse reflectance UV-visible spectroscopy with Tauc analysis

UV-visible and optical absorption spectroscopy

Co@Mn2DSBDC powder · Powder

Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.

Context: pristine_or_exchanged_framework
Measurement source: 5 · 3.1 · Fig. S3; Fig. S4; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tauc x-intercept bandgap	2.34 eV	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2
bandgap wavelength equivalent	530 nm	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2

diffuse reflectance UV-visible spectroscopy with Tauc analysis

UV-visible and optical absorption spectroscopy

Cu@Mn2DSBDC powder · Powder

Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.

Context: pristine_or_exchanged_framework
Measurement source: 5 · 3.1 · Fig. S3; Fig. S4; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tauc x-intercept bandgap	2.14 eV	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2
bandgap wavelength equivalent	579 nm	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2

diffuse reflectance UV-visible spectroscopy with Tauc analysis

UV-visible and optical absorption spectroscopy

as-prepared Mn2DSBDC powder · Powder

Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.

Context: pristine_or_exchanged_framework
Measurement source: 5 · 3.1 · Fig. S3; Fig. S4; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tauc x-intercept bandgap	2.43 eV	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2
bandgap wavelength equivalent	510 nm	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2

diffuse reflectance UV-visible spectroscopy with Tauc analysis

UV-visible and optical absorption spectroscopy

Ni@Mn2DSBDC powder · Powder

Shimadzu UV-2600 with integrating sphere; band gaps extracted from Tauc plots.

Context: pristine_or_exchanged_framework
Measurement source: 5 · 3.1 · Fig. S3; Fig. S4; Table S2

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Tauc x-intercept bandgapMarked as a best value within this paper	2.05 eV	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2
bandgap wavelength equivalent	605 nm	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S2

X-ray fluorescence (XRF)

Bulk elemental and compositional analysis

Co@Mn2DSBDC powder · Powder

Rigaku ZSX Primus II XRF spectrometer; at% exchanged cation with respect to Mn.

Context: pristine_or_exchanged_framework
Measurement source: 3 · 2.7 Standard characterization of MOFs · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
exchanged cation atomic percent with respect to Mn	10.2 at%	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S1

X-ray fluorescence (XRF)

Bulk elemental and compositional analysis

Cu@Mn2DSBDC powder · Powder

Rigaku ZSX Primus II XRF spectrometer; at% exchanged cation with respect to Mn.

Context: pristine_or_exchanged_framework
Measurement source: 3 · 2.7 Standard characterization of MOFs · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
exchanged cation atomic percent with respect to Mn	8.2 at%	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S1

X-ray fluorescence (XRF)

Bulk elemental and compositional analysis

Ni@Mn2DSBDC powder · Powder

Rigaku ZSX Primus II XRF spectrometer; at% exchanged cation with respect to Mn.

Context: pristine_or_exchanged_framework
Measurement source: 3 · 2.7 Standard characterization of MOFs · Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
exchanged cation atomic percent with respect to Mn	7.5 at%	—	—	SI Table Exact Reported	S6 · Supplementary Tables · Table S1