Measurement evidence
Dye-sensitized solar cells with new one-dimensional halide-bridged Cu(I)-Ni(II) heterometal coordination polymers containing hexamethylene dithiocarbamate ligand · Okubo T., Tanaka N., Anma H. et al. · Polymers · 2012 · 1613-1626
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
1a powder-pressed pellet · Pellet
Photoemission yield curve under atmospheric conditions.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| HOMO energy level | -5.24 eV | — | — | Text Rounded Reported | p006-p007 (journal p1618-p1619) · 3.2 · Figure 3 / Figure S2 |
| LUMO energy level | -3.90 eV | — | — | Text Rounded Reported | p007 (journal p1619) · 3.2 |
1b powder-pressed pellet · Pellet
Photoemission yield curve under atmospheric conditions.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| HOMO energy level | -5.23 eV | — | — | Text Rounded Reported | p006-p007 (journal p1618-p1619) · 3.2 · Figure 3 / Figure S2 |
| LUMO energy level | -3.66 eV | — | — | Text Rounded Reported | p007 (journal p1619) · 3.2 |
3 comparator coordination polymer · Powder
Photoemission yield curve for coordination polymer 3; SI Figure S2 is cited, but local SI image is unavailable.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| HOMO-LUMO gap comparator 3 | 1.01 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 |
| HOMO energy level | -5.28 eV | — | — | Text Rounded Reported | p006-p007 (journal p1618-p1619) · 3.2 · Figure 3 / Figure S2 |
| LUMO energy level | -4.27 eV | — | — | Text Rounded Reported | p007 (journal p1619) · 3.2 |
1a/KBr transmission pellet · Pellet
0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| relative d-d transition probability around 600 nm | 1a and 1b lower than 2a and 2b around 600 nm | — | — | Text Qualitative | p006 (journal p1618) · 3.2 · Figure S3 |
1b/KBr transmission pellet · Pellet
0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
2a/KBr transmission pellet · Pellet
0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
2b/KBr transmission pellet · Pellet
0.5 umol coordination polymer ground with 50 mg KBr for 5 min and pressed in a 13 mm pellet maker; spectra shown in SI Figure S3.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
1a/MgO diffuse-reflectance pellet · Pellet
0.01 mmol 1a doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge-transfer absorption band | around 380 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| d-d absorption band | around 640 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| HOMO-LUMO gap | 1.34 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 · Figure 2b |
| HOMO-LUMO gap comparator 2a | 1.48 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 |
1b/MgO diffuse-reflectance pellet · Pellet
0.01 mmol 1b doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge-transfer absorption band | around 380 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| d-d absorption band | around 640 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| HOMO-LUMO gap | 1.57 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 · Figure 2b |
| HOMO-LUMO gap comparator 2b | 1.48 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 |
Ni(Hm-dtc)2/MgO diffuse-reflectance pellet · Pellet
0.01 mmol complex doped in 80 mg MgO powder; U-4100 UV/VIS/NIR spectrophotometer.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| charge-transfer absorption band | around 380 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| d-d absorption band | around 640 nm | — | — | Text Approximate | p006 (journal p1618) · 3.2 · Figure 2 |
| HOMO-LUMO gap | 1.58 eV | — | — | Text Rounded Reported | p006 (journal p1618) · 3.2 · Figure 2b |