cMOF Evidence Base
Spectroscopy — New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene

Measurement evidence

Spectroscopy

New coordination polymers of 1,4-bis(2′-hydroxyphenylazomethine) phenylene · Hassan M.K., Abd-Alla M.A., Hasan R.M. · Journal of Macromolecular Science: Part A - Chemistry · 1990 · 1501-1512

15 measurement groups · 65 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FTIR/KBr disk

Infrared spectroscopy

BHPAP ligand crystals · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1502,1507-1508 · Experimental; Results · Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
aromatic C=C stretch1590 cm-1——Table
Exact Reported		1502,1507-1508 · Experimental; Results · Table 2
C=N stretch1620 cm-1——Table
Exact Reported		1502,1507-1508 · Experimental; Results · Table 2
phenolic C-O stretch1260 cm-1——Table
Exact Reported		1502,1507-1508 · Experimental; Results · Table 2
OH stretch3450-3100 cm-1 broad——Table
Range		1502,1507-1508 · Experimental; Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

BHPAP ligand crystals · Powder

DMF solution; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1504,1506 · Results and Discussion · Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
ligand absorption peak 1295 nm——Text
Exact Reported		1504 · Results and Discussion · Fig. 1
ligand absorption peak 2370 nm——Text
Exact Reported		1504 · Results and Discussion · Fig. 1

FTIR/KBr disk

Infrared spectroscopy

Cr-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1615 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1290 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-Cl stretch350 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch510 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch455 cm-1——Table
Exact Reported		1508 · Results · Table 2
coordinated-water rocking vibration855 cm-1——Table
Exact Reported		1508 · Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Cr-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1250 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2430 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3450 nm——Table
Exact Reported		1506 · Results · Table 1

FTIR/KBr disk

Infrared spectroscopy

Cu-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1610 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1280 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch515 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch440 cm-1——Table
Exact Reported		1508 · Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Cu-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1285 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2280 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3410 nm——Table
Exact Reported		1506 · Results · Table 1

FTIR/KBr disk

Infrared spectroscopy

Fe-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1615 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1285 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-Cl stretch345 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch510 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch438 cm-1——Table
Exact Reported		1508 · Results · Table 2
coordinated-water rocking vibration850 cm-1——Table
Exact Reported		1508 · Results · Table 2

Fe-57 Mossbauer spectroscopy

Mossbauer spectroscopy

Fe-BHPAP polychelate powder · Powder

Austin Science Associates constant acceleration drive with flyback mode; isomer shifts referenced to iron at room temperature.

Context
pristine coordination polymer
Measurement source
1503,1510-1511 · Measurements; Results · Fig. 4
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
iron oxidation/spin assignmenthigh-spin Fe(III) species——Text
Qualitative		1511 · Results and Discussion · Fig. 4
isomer shift0.35 mm/s relative to iron——Text
Exact Reported		1511 · Results and Discussion · Fig. 4
quadrupole splitting0.7 mm/s——Text
Exact Reported		1511 · Results and Discussion · Fig. 4

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Fe-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1252 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2380 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3405 nm——Table
Exact Reported		1506 · Results · Table 1

FTIR/KBr disk

Infrared spectroscopy

Mn-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1610 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1280 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch510 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch445 cm-1——Table
Exact Reported		1508 · Results · Table 2
coordinated-water rocking vibration850 cm-1——Table
Exact Reported		1508 · Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Mn-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1256 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2425 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3450 nm——Table
Exact Reported		1506 · Results · Table 1

FTIR/KBr disk

Infrared spectroscopy

Ni-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1612 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1280 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch520 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch440 cm-1——Table
Exact Reported		1508 · Results · Table 2
coordinated-water rocking vibration855 cm-1——Table
Exact Reported		1508 · Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Ni-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1285 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2385 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3412 nm——Table
Exact Reported		1506 · Results · Table 1

FTIR/KBr disk

Infrared spectroscopy

Ti-BHPAP polychelate powder · Powder

Perkin-Elmer 599 B, 4000-200 cm-1; KBr disk.

Context
pristine coordination polymer
Measurement source
1507-1510 · Results and Discussion · Table 2; Fig. 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
C=C aromatic stretch1590 cm-1——Table
Exact Reported		1508 · Results · Table 2
C=N stretch1618 cm-1——Table
Exact Reported		1508 · Results · Table 2
C-O phenolic stretch1290 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-Cl stretch370 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-N stretch515 cm-1——Table
Exact Reported		1508 · Results · Table 2
M-O stretch438 cm-1——Table
Exact Reported		1508 · Results · Table 2
coordinated-water rocking vibration850 cm-1——Table
Exact Reported		1508 · Results · Table 2

UV-visible spectroscopy

UV-visible and optical absorption spectroscopy

Ti-BHPAP polychelate powder · Powder

DMF solution of the polymeric chelate; Unicam SP 800 spectrophotometer.

Context
pristine coordination polymer
Measurement source
1503-1506 · Measurements; Results · Table 1; Fig. 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
lambda_max band 1245 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 2422 nm shoulder——Table
Exact Reported		1506 · Results · Table 1
lambda_max band 3452 nm——Table
Exact Reported		1506 · Results · Table 1