Spectroscopy — A semiconducting uranium-organic framework based on a tetrathiafulvalene derivative

Measurement evidence

Spectroscopy

A semiconducting uranium-organic framework based on a tetrathiafulvalene derivative · Zhai F., Li H., Gui D. et al. · Dalton Transactions · 2022

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

FTIR/ATR spectroscopy; Bruker NICOLET iS50 with diamond ATR reflectance accessory.

SCU-125 bulk powder/ground crystals · Powder

Spectral data collected at 25 deg C +/- 2 deg C.

Temperature
298
Geometry
ATR reflectance
Context
pristine_framework
Measurement source
SI p001 · Characterization · Figure 3a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Uranyl vibration FTIR peak924.7 cm^-1Text
Exact Reported
16449 · Results · Figure 3a

UV-vis diffuse-reflectance spectroscopy; Shimadzu UV3600 with integrating sphere and BaSO4 reference.

SCU-125 bulk powder/ground crystals · Powder

Recorded from 200 to 800 nm; spectral data collected at 25 deg C +/- 2 deg C.

Temperature
298
Geometry
Diffuse reflectance
Context
pristine_framework
Measurement source
SI p001 · Characterization · Figure S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Bandgap-indication wavelength705.8 nmFigure Axis
Rounded Reported
SI p004 · Figure S2 · Figure S2
Optical energy gapMarked as a best value within this paper1.8 eVText
Rounded Reported
16449 · Results · Figure S2

X-ray photoelectron spectroscopy (XPS).

SCU-125 bulk powder/ground crystals · Powder

U 4f and S 2p spectra used to identify uranyl and sulfur valence states.

Context
pristine_framework
Measurement source
16449 · Results · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
S 2p1/2 binding energy165.1 eVText
Exact Reported
16449 · Results · Figure S3
S 2p3/2 binding energy163.9 eVText
Exact Reported
16449 · Results · Figure S3
U 4f5/2 binding energy393.05 eVText
Exact Reported
16449 · Results · Figure S3
U 4f7/2 binding energy382.2 eVText
Exact Reported
16449 · Results · Figure S3