Complete recipeSource: Both
Route 1: Solvothermal
SI p001 · Chemicals and synthesis
Metal precursorsUO2(NO3)2.6H2O, 13 mg (0.03 mmol)
Linker precursorstetrathafulvalene-3,4,5,6-tetrakis(4-benzoic acid) (H4TTFTB), 6.9 mg (0.01 reported without unit)
Solvents1.5 mL water and 1.5 mL N,N-dimethylformamide (DMF)
Additives20 uL concentrated HNO3
AtmosphereSealed 10 mL scintillation vial; gas atmosphere not specified.
Temperature120
Time72
Work-upSonicated for 15 min before heating; dark brown crystals collected and washed with DMF and alcohol three times each.
ActivationProducts dried at 60 deg C.
Scalability contextSmall-vial batch synthesis; no yield or scale-up study reported.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | tetrathafulvalene-3,4,5,6-tetrakis(4-benzoic acid) (H4TTFTB) | 6.9 mg (0.01) | SI p001 · Chemicals and synthesis |
| Solvent | water | 1.5 mL | SI p001 · Chemicals and synthesis |
| Solvent | N,N-dimethylformamide (DMF) | 1.5 mL | SI p001 · Chemicals and synthesis |
| Metal Source | UO2(NO3)2.6H2O | 13 mg (0.03 mmol) | SI p001 · Chemicals and synthesis |
| Acid | concentrated HNO3 | 20 uL · concentrated | SI p001 · Chemicals and synthesis |