Measurement evidence
A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence · Scheurle P.I., Mahringer A., Jakowetz A.C. et al. · Nanoscale · 2019 · 20949-20955
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
ANMOF-74(Zn) bulk powder · Powder
Series-level supporting characterisation for ANMOF-74(Zn/Mg/Ni/Co/Mn); sample_key anchors the measurement to a representative ANMOF sample while notes describe the series scope.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| EDX precursor-anion impurity check | no impurities arising from precursor anions observed by EDX | — | — | Caption Qualitative | 20951 · Results and discussion · Fig. S11 |
ANMOF-74(Co) bulk powder · Powder
UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct optical band gap ANMOF-74(Co) | 2.94 eV | — | — | Figure Axis Rounded Reported | S22 · Tauc plots of the ANMOF-74 series · Figure S5 |
| PL emission maximum ANMOF-74(Co) | 441 nm | — | — | Visual Estimate Approximate | 20952-20953 · Results and discussion · Fig. 5 |
ANMOF-74(Mg) bulk powder · Powder
UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct optical band gap ANMOF-74(Mg) | 2.92 eV | — | — | Figure Axis Rounded Reported | S22 · Tauc plots of the ANMOF-74 series · Figure S5 |
| ANMOF-74(Mg) CIE 1931 x coordinate | 0.16881 | — | — | Figure Axis Exact Reported | S24 · Photoluminescence quantum yield (PLQY) and CIE color space · Figure S8 |
| ANMOF-74(Mg) CIE 1931 y coordinate | 0.15488 | — | — | Figure Axis Exact Reported | S24 · Photoluminescence quantum yield (PLQY) and CIE color space · Figure S8 |
| ANMOF-74(Mg) CIE 1976 u' coordinate | 0.14936 | — | — | Figure Axis Exact Reported | S24 · Photoluminescence quantum yield (PLQY) and CIE color space · Figure S8 |
| ANMOF-74(Mg) CIE 1976 v' coordinate | 0.30833 | — | — | Figure Axis Exact Reported | S24 · Photoluminescence quantum yield (PLQY) and CIE color space · Figure S8 |
| PL emission maximum ANMOF-74(Mg) | 438 nm | — | — | Text Rounded Reported | 20952-20953 · Results and discussion · Fig. 5 |
| Photoluminescence quantum yield ANMOF-74(Mg)Marked as a best value within this paper | 2.5% (Figure S7 shows 2.5 ± 0.5%) | — | ±0.5% from figure legend | Figure Axis Rounded Reported | S24 · Photoluminescence quantum yield (PLQY) and CIE color space · Figure S7 |
ANMOF-74(Mn) bulk powder · Powder
UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct optical band gap ANMOF-74(Mn) | 2.92 eV | — | — | Figure Axis Rounded Reported | S22 · Tauc plots of the ANMOF-74 series · Figure S5 |
| PL emission maximum ANMOF-74(Mn) | 444 nm | — | — | Visual Estimate Approximate | 20952-20953 · Results and discussion · Fig. 5 |
ANMOF-74(Ni) bulk powder · Powder
UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct optical band gap ANMOF-74(Ni) | 2.95 eV | — | — | Figure Axis Rounded Reported | S22 · Tauc plots of the ANMOF-74 series · Figure S5 |
| PL emission maximum ANMOF-74(Ni) | 444 nm | — | — | Visual Estimate Approximate | 20952-20953 · Results and discussion · Fig. 5 |
ANMOF-74(Zn) bulk powder · Powder
UV-vis in diffuse reflectance with Kubelka-Munk conversion; PL measured with 378 nm excitation under argon atmosphere.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Direct optical band gap ANMOF-74(Zn) | 2.86 eV | — | — | Text Rounded Reported | 20952 · Results and discussion · Fig. 5 |
| PL emission maximum ANMOF-74(Zn) | 570 nm | — | — | Text Rounded Reported | 20952-20953 · Results and discussion · Fig. 5 |
ANMOF-74(Co) bulk powder · Powder
TCSPC traces recorded at respective emission maxima; triexponential fits for MOFs; fitting error reported, actual setup resolution around 100 ps.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| tau1 PL lifetime component ANMOF-74(Co) | 0.064 ns; fractional intensity 80.5% | — | ±0.002 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau2 PL lifetime component ANMOF-74(Co) | 0.79 ns; fractional intensity 15.5% | — | ±0.06 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau3 PL lifetime component ANMOF-74(Co) | 7.0 ns; fractional intensity 4.0% | — | ±2 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
ANMOF-74(Mg) bulk powder · Powder
TCSPC traces recorded at respective emission maxima; triexponential fits for MOFs; fitting error reported, actual setup resolution around 100 ps.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| tau1 PL lifetime component ANMOF-74(Mg) | 0.169 ns; fractional intensity 28.7% | — | ±0.006 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau2 PL lifetime component ANMOF-74(Mg) | 1.03 ns; fractional intensity 50.0% | — | ±0.02 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau3 PL lifetime component ANMOF-74(Mg) | 4.9 ns; fractional intensity 21.3% | — | ±0.12 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
ANMOF-74(Mn) bulk powder · Powder
TCSPC traces recorded at respective emission maxima; triexponential fits for MOFs; fitting error reported, actual setup resolution around 100 ps.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| tau1 PL lifetime component ANMOF-74(Mn) | 0.065 ns; fractional intensity 48.3% | — | ±0.003 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau2 PL lifetime component ANMOF-74(Mn) | 0.89 ns; fractional intensity 28.8% | — | ±0.06 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau3 PL lifetime component ANMOF-74(Mn) | 5.1 ns; fractional intensity 22.9% | — | ±0.4 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
ANMOF-74(Ni) bulk powder · Powder
TCSPC traces recorded at respective emission maxima; triexponential fits for MOFs; fitting error reported, actual setup resolution around 100 ps.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| tau1 PL lifetime component ANMOF-74(Ni) | 0.065 ns; fractional intensity 55.3% | — | ±0.004 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau2 PL lifetime component ANMOF-74(Ni) | 0.8 ns; fractional intensity 31.9% | — | ±0.06 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau3 PL lifetime component ANMOF-74(Ni) | 5.6 ns; fractional intensity 12.8% | — | ±1.0 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
ANMOF-74(Zn) bulk powder · Powder
TCSPC traces recorded at respective emission maxima; triexponential fits for MOFs; fitting error reported, actual setup resolution around 100 ps.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| tau1 PL lifetime component ANMOF-74(Zn) | 0.162 ns; fractional intensity 22.9% | — | ±0.012 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau2 PL lifetime component ANMOF-74(Zn) | 0.79 ns; fractional intensity 59.5% | — | ±0.03 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
| tau3 PL lifetime component ANMOF-74(Zn) | 3.4 ns; fractional intensity 17.6% | — | ±0.2 | SI Table Exact Reported | S23 · Time-correlated single photon counting (TCSPC) traces · Table S1 |
ANMOF-74(Zn) bulk powder · Powder
Series-level supporting characterisation for ANMOF-74(Zn/Mg/Ni/Co/Mn); sample_key anchors the measurement to a representative ANMOF sample while notes describe the series scope.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| XPS detected elements in ANMOF-74 series | respective metal, C, O and nitrogen attributed to DMF residues | — | — | Text Qualitative | 20950-20951 · Results and discussion · Fig. S13-S17 |