Scheurle P.I., Mahringer A., Jakowetz A.C. et al. · Nanoscale · 2019 · 20949-20955
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The series combines defined porosity, luminescence and electrical conductivity in a fixed MOF matrix, suggesting optoelectronic, sensing and charge-storage relevance.
Caveat: Application relevance is prospective; no device/application performance was measured.
20954 · Conclusions · Linked to 3 structured results
ANMOF-74(Zn/Mg/Ni/Co/Mn) crystallise as trigonal R3 MOF-74 topology frameworks with hexagonal one-dimensional channels.
Caveat: Based on Rietveld-refined PXRD against simulated model structures, not single-crystal structures.
20950-20951 · Results and discussion · Fig. 2 · Linked to 5 structured results
All ANMOF-74 materials are microporous and have BET surface areas above 1000 m2 g-1.
Caveat: Porosity values are from activated powders, not conductivity pellets.
20951-20952 · Results and discussion · Fig. 3 · Linked to 5 structured results
The anthracene core in the ANMOF-74 backbone is attributed to enhanced electrical conductivity versus electron-poor 2,5-dihydroxyterephthalate MOF-74 controls.
Caveat: Mechanism is an author attribution; conductivity values are direct pellet measurements but microscopic transport pathway is inferred.
20951-20953 · Results and discussion · Table 1 · Linked to 5 structured results
Measured conductivities remain modest; authors postulate charge transport occurs mostly through metal-oxo chains because adjacent anthracene units are separated by large stacking distances.
Caveat: Postulated transport mechanism rather than directly measured pathway.
20952 · Results and discussion · Fig. 1B; Table 1 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| ANMOF-74(Co) | Co18C252H126O63 · DMF (elemental-analysis formula, vacuum treated)Co2+ in helical metal-oxo chains · 4,4'-(anthracene-9,10-diyl)bis(2-hydroxybenzoic acid), ABHB | 3D · PristineAnthracene-based MOF-74 topology; trigonal R3 (146); one-dimensional hexagonal channels with about 2 nm apertures. | 20949-20950 · Abstract; Results and discussion · Fig. 1 |
| ANMOF-74(Mg) | Mg18C252H126O63 · DMF (elemental-analysis formula, vacuum treated)Mg2+ in helical metal-oxo chains · 4,4'-(anthracene-9,10-diyl)bis(2-hydroxybenzoic acid), ABHB | 3D · PristineAnthracene-based MOF-74 topology; trigonal R3 (146); one-dimensional hexagonal channels with about 2 nm apertures. | 20949-20950 · Abstract; Results and discussion · Fig. 1 |
| ANMOF-74(Mn) | Mn18C252H126O63 · DMF (elemental-analysis formula, vacuum treated)Mn2+ in helical metal-oxo chains · 4,4'-(anthracene-9,10-diyl)bis(2-hydroxybenzoic acid), ABHB | 3D · PristineAnthracene-based MOF-74 topology; trigonal R3 (146); one-dimensional hexagonal channels with about 2 nm apertures. | 20949-20950 · Abstract; Results and discussion · Fig. 1 |
| ANMOF-74(Ni) | Ni18C252H126O63 · DMF (elemental-analysis formula, vacuum treated)Ni2+ in helical metal-oxo chains · 4,4'-(anthracene-9,10-diyl)bis(2-hydroxybenzoic acid), ABHB | 3D · PristineAnthracene-based MOF-74 topology; trigonal R3 (146); one-dimensional hexagonal channels with about 2 nm apertures. | 20949-20950 · Abstract; Results and discussion · Fig. 1 |
| ANMOF-74(Zn) | Zn18C252H126O63 · DMF (elemental-analysis formula, vacuum treated)Zn2+ in helical metal-oxo chains · 4,4'-(anthracene-9,10-diyl)bis(2-hydroxybenzoic acid), ABHB | 3D · PristineAnthracene-based MOF-74 topology; trigonal R3 (146); one-dimensional hexagonal channels with about 2 nm apertures. | 20949-20950 · Abstract; Results and discussion · Fig. 1 |
| MOF-74(Co)Browse family: Co₂(DOBDC) / Co–MOF-74 / CPO-27-Co | not explicitly reportedCo2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid | 3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison. | 20949-20951 · Abstract; Results and discussion · Table 1 |
| MOF-74(Mg)Browse family: Mg₂(DOBDC) / Mg–MOF-74 / CPO-27-Mg | not explicitly reportedMg2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid | 3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison. | 20949-20951 · Abstract; Results and discussion · Table 1 |
| MOF-74(Mn)Browse family: Mn₂(DOBDC) / Mn–MOF-74 / CPO-27-Mn | not explicitly reportedMn2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid | 3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison. | 20949-20951 · Abstract; Results and discussion · Table 1 |
| MOF-74(Ni)Browse family: Ni₂(DOBDC) / Ni–MOF-74 / CPO-27-Ni | not explicitly reportedNi2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid | 3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison. | 20949-20951 · Abstract; Results and discussion · Table 1 |
| MOF-74(Zn)Browse family: Zn₂(DOBDC) / Zn–MOF-74 / CPO-27-Zn | not explicitly reportedZn2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid | 3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison. | 20949-20951 · Abstract; Results and discussion · Table 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| ANMOF-74(Co) pelletresearch_0165__mat__an_mof74_co | Pellet · Target Sample · Pristine Framework | pellet fabricated from 100 mg bulk material with 1 cm diameter for electrical conductivity measurement | S4 · Preparation of ANMOF-74 and MOF-74 pellets |
| ANMOF-74(Co) bulk powderresearch_0165__mat__an_mof74_co | Powder · Target Sample · Pristine Framework | washed, activated at 120 deg C, crystalline bulk powder; used for PXRD, porosity, microscopy, spectroscopy and supporting analyses | S10-S11 · Anthracene-based MOF-74 (ANMOF-74) synthesis |
| ANMOF-74(Mg) pelletresearch_0165__mat__an_mof74_mg | Pellet · Target Sample · Pristine Framework | pellet fabricated from 100 mg bulk material with 1 cm diameter for electrical conductivity measurement | S4 · Preparation of ANMOF-74 and MOF-74 pellets |
| ANMOF-74(Mg) bulk powderresearch_0165__mat__an_mof74_mg | Powder · Target Sample · Pristine Framework | washed, activated at 120 deg C, crystalline bulk powder; used for PXRD, porosity, microscopy, spectroscopy and supporting analyses | S10-S11 · Anthracene-based MOF-74 (ANMOF-74) synthesis |
| ANMOF-74(Mn) pelletresearch_0165__mat__an_mof74_mn | Pellet · Target Sample · Pristine Framework | pellet fabricated from 100 mg bulk material with 1 cm diameter for electrical conductivity measurement | S4 · Preparation of ANMOF-74 and MOF-74 pellets |
| ANMOF-74(Mn) bulk powderresearch_0165__mat__an_mof74_mn | Powder · Target Sample · Pristine Framework | washed, activated at 120 deg C, crystalline bulk powder; used for PXRD, porosity, microscopy, spectroscopy and supporting analyses | S10-S11 · Anthracene-based MOF-74 (ANMOF-74) synthesis |
| ANMOF-74(Ni) pelletresearch_0165__mat__an_mof74_ni | Pellet · Target Sample · Pristine Framework | pellet fabricated from 100 mg bulk material with 1 cm diameter for electrical conductivity measurement | S4 · Preparation of ANMOF-74 and MOF-74 pellets |
| ANMOF-74(Ni) bulk powderresearch_0165__mat__an_mof74_ni | Powder · Target Sample · Pristine Framework | washed, activated at 120 deg C, crystalline bulk powder; used for PXRD, porosity, microscopy, spectroscopy and supporting analyses | S10-S11 · Anthracene-based MOF-74 (ANMOF-74) synthesis |
| ANMOF-74(Zn) pelletresearch_0165__mat__an_mof74_zn | Pellet · Target Sample · Pristine Framework | pellet fabricated from 100 mg bulk material with 1 cm diameter for electrical conductivity measurement | S4 · Preparation of ANMOF-74 and MOF-74 pellets |
| ANMOF-74(Zn) bulk powderresearch_0165__mat__an_mof74_zn | Powder · Target Sample · Pristine Framework | washed, activated at 120 deg C, crystalline bulk powder; used for PXRD, porosity, microscopy, spectroscopy and supporting analyses | S10-S11 · Anthracene-based MOF-74 (ANMOF-74) synthesis |
| MOF-74(Co) control pelletresearch_0165__mat__mof74_co | Pellet · Pristine Control · Pristine Framework | activated/vacuum dried regular MOF-74 powder compressed into pellet for conductivity comparison | 20951 · Results and discussion · Table 1 |
| MOF-74(Co) control powderresearch_0165__mat__mof74_co | Powder · Pristine Control · Pristine Framework | washed and dried under reduced pressure; vacuum-dried/activated before pellet conductivity testing according to main text | S11-S13 · MOF-74 synthesis |
| MOF-74(Mg) control pelletresearch_0165__mat__mof74_mg | Pellet · Pristine Control · Pristine Framework | activated/vacuum dried regular MOF-74 powder compressed into pellet for conductivity comparison | 20951 · Results and discussion · Table 1 |
| MOF-74(Mg) control powderresearch_0165__mat__mof74_mg | Powder · Pristine Control · Pristine Framework | washed and dried under reduced pressure; vacuum-dried/activated before pellet conductivity testing according to main text | S11-S13 · MOF-74 synthesis |
| MOF-74(Mn) control pelletresearch_0165__mat__mof74_mn | Pellet · Pristine Control · Pristine Framework | activated/vacuum dried regular MOF-74 powder compressed into pellet for conductivity comparison | 20951 · Results and discussion · Table 1 |
| MOF-74(Mn) control powderresearch_0165__mat__mof74_mn | Powder · Pristine Control · Pristine Framework | washed and dried under reduced pressure; vacuum-dried/activated before pellet conductivity testing according to main text | S11-S13 · MOF-74 synthesis |
| MOF-74(Ni) control pelletresearch_0165__mat__mof74_ni | Pellet · Pristine Control · Pristine Framework | activated/vacuum dried regular MOF-74 powder compressed into pellet for conductivity comparison | 20951 · Results and discussion · Table 1 |
| MOF-74(Ni) control powderresearch_0165__mat__mof74_ni | Powder · Pristine Control · Pristine Framework | washed and dried under reduced pressure; vacuum-dried/activated before pellet conductivity testing according to main text | S11-S13 · MOF-74 synthesis |
| MOF-74(Zn) control pelletresearch_0165__mat__mof74_zn | Pellet · Pristine Control · Pristine Framework | activated/vacuum dried regular MOF-74 powder compressed into pellet for conductivity comparison | 20951 · Results and discussion · Table 1 |
| MOF-74(Zn) control powderresearch_0165__mat__mof74_zn | Powder · Pristine Control · Pristine Framework | washed and dried under reduced pressure; vacuum-dried/activated before pellet conductivity testing according to main text | S11-S13 · MOF-74 synthesis |