Source-verified familyIdentity or context cautions

Mn₂(DOBDC) / Mn–MOF-74 / CPO-27-Mn

This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.

6primary papers
6material records
13linked samples
10linked measurements
14linked results
2015–2024publication span

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  • Several formulas or formula descriptions are reported

This metal-specific MOF-74/CPO-27 discovery family includes source-verified coordinated-solvent states, whose full formula and activation state remain attached to each record. Reviewed members are classified as 3D frameworks containing 1D channels; pore-direction and structural descriptions remain visible below. Guest-loaded, substituted-linker, mixed-metal and phase-unverified M₂(DOBDC) films remain separate materials.

Evidence coverage

Paper counts are material-linked through samples and measurements; technique groups are not value rankings.

Publication timeline

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Primary papers

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6 papers

Per-paper identity records

Raw names, formulas and structural assignments remain separate; no consensus value is inferred.

Show 6 material identity records
Paper and reported nameFormula and componentsStructure contextSource
Mn-MOF-742024 · From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworksMn2(dobdc) framework, reported as Mn-MOF-74Mn2+ open metal sites in MOF-74 · 2,5-dihydroxyterephthalic acid derived dobdc linker3D · PristineIsostructural M-MOF-74 parent framework; open d-shell host.S-2 · Syntheses
Mn-MOF-74 nanoparticles2023 · Toward High-Performance Metal–Organic-Framework-Based Quasi-Solid-State Electrolytes: Tunable Structures and Electrochemical PropertiesMn2(DOBDC)Open Mn2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC3D · PristineMOF-74 framework confirmed by PXRD.SI p.S-19 · Supplementary Figures and Tables · Figure S6
Mn-CPO-27 (Mn2-DOBDC)2021 · An Electrically Conducting Li-Ion Metal-Organic FrameworkMn2-DOBDCMn(II) CPO-27 / MOF-74 nodes · DOBDC linker bound in CPO-27 topology3D · PristineCPO-27 / MOF-74 compositional analogue used as control.4 · 1.2.4. Synthesis of Mn-CPO-27 · Figure 2; Figure 4
MOF-74(Mn)2019 · A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescencenot explicitly reportedMn2+ in regular MOF-74 metal-oxo chains · 2,5-dihydroxy-1,4-benzenedicarboxylic acid / 2,5-dihydroxyterephthalic acid3D · PristineOriginal MOF-74 isostructure prepared as pristine control for conductivity comparison.20949-20951 · Abstract; Results and discussion · Table 1
Mn2(DOBDC)(DMF)22017 · Is iron unique in promoting electrical conductivity in MOFs?Mn2(DOBDC)(DMF)2Mn2+ · DOBDC; DMF-coordinated3D · Pristinehoneycomb structure with 1D tubular pores4451 · Experimental results · Fig. 1
Mn2(DOBDC)2015 · Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)Mn2(DOBDC)(DMF)2.x(DMF) and Mn2(DOBDC)(DMF)2 sample statesMn2+ chains, (-Mn-O-)inf secondary building units · DOBDC4- = 2,5-dihydroxybenzene-1,4-dicarboxylate3D · PristineMOF-74 analogue used as the Mn/O comparator.S9 · Mn2(DOBDC)(DMF)2