Electrochemistry Application — Toward High-Performance Metal–Organic-Framework-Based Quasi-Solid-State Electrolytes: Tunable Structures and Electrochemical Properties

10 measurement groups · 17 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Galvanostatic Li/LiCoO2 cell testing

Galvanostatic cycling

Li@Zn-MOF-74/Li-IL electrolyte pellet, 1:1.5 · Pellet

Li@Zn-MOF-74/Li-IL electrolyte; 30 C; 2.5 V to cut-off voltages 4.2-4.6 V; CCCV at higher rates.

Temperature: 303
Geometry: Li||Li@Zn-MOF-74/Li-IL||LiCoO2 coin cell
Context: high-voltage application cell
Measurement source: article p.12 · Demonstration for Li-ion Batteries · Figure 8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LiCoO2 specific capacity at 0.1 C	131 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8d,e
LiCoO2 specific capacity at 0.1 C return	129 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8d,e
LiCoO2 specific capacity at 0.2 C	123 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8d,e
LiCoO2 specific capacity at 0.5 C	111 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8d,e
LiCoO2 specific capacity at 1 C	75 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8d,e
LiCoO2 initial capacity at 4.6 V cut-off	128 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8f

Galvanostatic Li/LiFePO4 cell testing

Galvanostatic cycling

Li@Zn-MOF-74/Li-IL electrolyte pellet, 1:1.5 · Pellet

Li@Zn-MOF-74/Li-IL electrolyte sandwiched between LiFePO4 cathode and Li metal; 30 C; 2.5-4.2 V.

Temperature: 303
Geometry: Li||Li@Zn-MOF-74/Li-IL||LiFePO4 coin cell
Context: application cell using best composite electrolyte
Measurement source: article p.12 · Demonstration for Li-ion Batteries · Figure 8

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LiFePO4 specific capacity at 0.1 C	152 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8a,b
LiFePO4 specific capacity at 1 C	94 mAh g-1	—	—	Text Exact Reported	article p.12 · Demonstration for Li-ion Batteries · Figure 8a,b
LiFePO4 cycling retentionMarked as a best value within this paper	>500 cycles at 0.5 C with about 90% capacity retention	—	—	Text Approximate	article p.12 · Demonstration for Li-ion Batteries · Figure 8c

Linear sweep voltammetry

Voltammetry

Li@Co-MOF-74/Li-IL electrolyte pellet · Pellet

0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: redox-active M-MOF-74 composite electrolyte
Measurement source: SI p.S-26 · Figure S13 caption · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.3-4.5 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@Cu-MOF-74/Li-IL electrolyte pellet · Pellet

0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: redox-active M-MOF-74 composite electrolyte
Measurement source: SI p.S-26 · Figure S13 caption · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.1-4.9 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@HKUST-1/Li-IL electrolyte pellet · Pellet

Cu foil or stainless-steel working electrode, Li foil counter/reference; 0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: composite MOF electrolyte
Measurement source: SI p.S-8 · Linear sweep voltammetry

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.5-5.4 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@Mg-MOF-74/Li-IL electrolyte pellet · Pellet

Cu foil or stainless-steel working electrode, Li foil counter/reference; 0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: composite MOF electrolyte
Measurement source: SI p.S-8 · Linear sweep voltammetry

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability windowMarked as a best value within this paper	0-5.6 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@Mn-MOF-74/Li-IL electrolyte pellet · Pellet

0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: redox-active M-MOF-74 composite electrolyte
Measurement source: SI p.S-26 · Figure S13 caption · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.1-5.0 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@MOF-5/Li-IL electrolyte pellet · Pellet

Cu foil or stainless-steel working electrode, Li foil counter/reference; 0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: composite MOF electrolyte
Measurement source: SI p.S-8 · Linear sweep voltammetry

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.7-5.6 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@Ni-MOF-74/Li-IL electrolyte pellet · Pellet

0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: redox-active M-MOF-74 composite electrolyte
Measurement source: SI p.S-26 · Figure S13 caption · Figure S13

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.7-4.3 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13

Linear sweep voltammetry

Voltammetry

Li@Zn-MOF-74/Li-IL electrolyte pellet, 1:1.5 · Pellet

Cu foil or stainless-steel working electrode, Li foil counter/reference; 0.5 mV s-1 at 30 C; +/-5 uA cm-2 threshold.

Temperature: 303
Geometry: Li/electrolyte/working-electrode half cell
Context: composite MOF electrolyte
Measurement source: SI p.S-8 · Linear sweep voltammetry

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
electrochemical stability window	0.2-5.2 V	—	—	SI Table Range	SI p.S-96 · Comparison of MOF electrolytes · Table S13