Dong P., Zhang X., Hiscox W. et al. · Advanced Materials · 2023 · 2211841
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Li@Zn-MOF-74/Li-IL combines high ionic conductivity, high transference number, and stable battery cycling with LiFePO4 and LiCoO2 cathodes at 30 C.
Caveat: Battery tests used small coin cells and about 5 uL Li-IL added to cathode for porous-cathode ion diffusion.
article p.12 · Conclusion · Linked to 4 structured results
Li-IL binder is required to provide interparticle ion diffusion; binder-free Li@MOF pellets showed open-circuit-like high resistance.
Caveat: Pure Li@MOF conductivities are reported qualitatively as huge bulk resistance rather than tabulated values.
SI p.S-93 · Supplementary Note regarding pure Li@MOF electrolytes · Figures S75-S77 · Linked to 2 structured results
MOF electrolytes with non-redox-active metal sites show wider electrochemical stability windows than analogues with redox-active metal centres.
Caveat: Stability windows are thresholded by +/-5 uA cm-2 LSV/CV criteria and depend on electrolyte composition.
article p.4 · Stability and Ion-Transport Properties · Figure 3g · Linked to 4 structured results
Pore aperture governs LiTFSI uptake, which in turn controls ionic conductivity across the Li@MOF/Li-IL electrolyte series.
Caveat: DME uptake and open-metal-site interactions also influence solvation and transport.
article p.8 · Solvation Structures · Figure 5 · Linked to 6 structured results
Open metal sites dissociate LiTFSI and immobilise TFSI- anions while allowing solvated Li+ transport, increasing transference number.
Caveat: Cluster DFT models simplify pore steric effects; XANES cannot distinguish whether TFSI- or DME coordinates to Zn2+.
article p.11 · Li-Ion Transport in MOFs · Figure 7 · Linked to 4 structured results
Solvated Li+ ions diffuse faster via a DME vehicle mechanism than de-solvated ions via hopping in Li@MOFs.
Caveat: T1 is an indirect mobility proxy; AIMD production length was 50 ps.
article p.8 · Solvation Structures · Figure 5d · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co-MOF-74 nanoparticlesBrowse family: Co₂(DOBDC) / Co–MOF-74 / CPO-27-Co | Co2(DOBDC)Open Co2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework confirmed by PXRD. | SI p.S-19 · Supplementary Figures and Tables · Figure S6 |
| Cu-MOF-74 nanoparticlesBrowse family: Cu₂(DOBDC) / Cu–MOF-74 / CPO-27-Cu | Cu2(DOBDC)Open Cu2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework; phase-pure nanoparticle sample selected at ligand/TEA 1:4. | SI p.S-18 · Supplementary Figures and Tables · Table S2 |
| HKUST-1 nanoparticlesBrowse family: HKUST-1 / Cu₃(BTC)₂ | Cu3(BTC)2; BTC = benzene-1,3,5-tricarboxylateCu2 paddle-wheel units; open Cu2+ sites exposed only toward pore 2. · H3BTC-derived BTC linker | 3D · Pristine3D-channel multimodal pores; pore 1 about 11 A without open Cu2+ sites and pore 2 about 13.5 A with open Cu2+ sites; ion-conducting aperture reported as 6.9 A. | article p.3 · Figure 1 caption · Figure 1 |
| Li-IL binder control | 1 M LiTFSI in Pyr14TFSINot a MOF. · Not applicable | unknown · CompositeIonic-liquid binder used as an ion-conductive composite component and control electrolyte. | SI p.S-6 · Preparation of Li@MOFs particles and Li@MOF/Li-IL electrolytes |
| Mg-MOF-74 nanoparticlesBrowse family: Mg₂(DOBDC) / Mg–MOF-74 / CPO-27-Mg | Mg2(DOBDC)Open Mg2+ sites; non-redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework; hollow aggregates of nanoparticles in this synthesis. | SI p.S-79 · Supplementary note · Table S10 |
| Mn-MOF-74 nanoparticlesBrowse family: Mn₂(DOBDC) / Mn–MOF-74 / CPO-27-Mn | Mn2(DOBDC)Open Mn2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework confirmed by PXRD. | SI p.S-19 · Supplementary Figures and Tables · Figure S6 |
| MOF-5 nanoparticles | Zn4O(BDC)3; BDC = benzene-1,4-dicarboxylateZn4O secondary building units without open metal sites. · H2BDC-derived BDC linker | 3D · Pristine3D-channel multimodal pores; pore aperture about 8 A and no open metal sites. | article p.3 · Figure 1 caption · Figure 1 |
| Ni-MOF-74 nanoparticlesBrowse family: Ni₂(DOBDC) / Ni–MOF-74 / CPO-27-Ni | Ni2(DOBDC)Open Ni2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework confirmed by PXRD. | SI p.S-19 · Supplementary Figures and Tables · Figure S6 |
| Zn-MOF-74 nanoparticlesBrowse family: Zn₂(DOBDC) / Zn–MOF-74 / CPO-27-Zn | Zn2(DOBDC); DOBDC = 2,5-dioxidoterephthalateOpen Zn2+ sites in MOF-74 chains; non-redox-active metal centre in this study. · 2,5-dihydroxyterephthalic acid-derived DOBDC linker | 3D · PristineMOF-74 framework with 1D channel pore, pore aperture about 10 A and open-metal-site density 4.4 sites nm-3. | article p.3 · Figure 1 caption · Figure 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Co-MOF-74 nanoparticlesresearch_0309__mat__co_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| Cu-MOF-74 nanoparticlesresearch_0309__mat__cu_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| HKUST-1 nanoparticlesresearch_0309__mat__hkust_1 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| Li@Co-MOF-74 particlesresearch_0309__mat__co_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Co-MOF-74/Li-IL electrolyte pelletresearch_0309__mat__co_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@Cu-MOF-74 particlesresearch_0309__mat__cu_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Cu-MOF-74/Li-IL electrolyte pelletresearch_0309__mat__cu_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@HKUST-1 particlesresearch_0309__mat__hkust_1 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@HKUST-1/Li-IL electrolyte pelletresearch_0309__mat__hkust_1 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li-IL binder controlresearch_0309__mat__li_il_binder_control | Unknown · Pristine Control · Composite | 1 M LiTFSI in Pyr14TFSI measured as binder/control. | SI p.S-28 · Figure S15 caption · Figure S15 |
| Li@Mg-MOF-74 particlesresearch_0309__mat__mg_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Mg-MOF-74/Li-IL electrolyte pelletresearch_0309__mat__mg_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@Mn-MOF-74 particlesresearch_0309__mat__mn_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Mn-MOF-74/Li-IL electrolyte pelletresearch_0309__mat__mn_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@MOF-5 particlesresearch_0309__mat__mof_5 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@MOF-5/Li-IL electrolyte pelletresearch_0309__mat__mof_5 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@Ni-MOF-74 particlesresearch_0309__mat__ni_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Ni-MOF-74/Li-IL electrolyte pelletresearch_0309__mat__ni_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@Zn-MOF-74 particlesresearch_0309__mat__zn_mof_74 | Powder · Target Sample · Guest Loaded | MOF particles soaked in 1 M LiTFSI/DME, washed with DME, and dried at 50 C under vacuum unless specified. | SI p.S-6 · Preparation of Li@MOFs particles |
| Li@Zn-MOF-74/Li-IL electrolyte pellet, 1:1 controlresearch_0309__mat__zn_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Li@Zn-MOF-74/Li-IL electrolyte pellet, 1:1.5research_0309__mat__zn_mof_74 | Pellet · Composite Sample · Composite | Li@MOF particles mixed with Li-IL binder, dried at 120 C, ground, and cold-pressed under about 4000 psi.about 300-310 um for Zn-MOF-74/Li-IL; pellet diameter 16 mm | SI pp.S-6-S-7 · Preparation of Li@MOF/Li-IL electrolytes · Figure S9; Figure S10 |
| Mg-MOF-74 hollow nanoparticle aggregatesresearch_0309__mat__mg_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| Mn-MOF-74 nanoparticlesresearch_0309__mat__mn_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| MOF-5 nanoparticlesresearch_0309__mat__mof_5 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| Ni-MOF-74 nanoparticlesresearch_0309__mat__ni_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |
| Pure Li@HKUST-1 pellet without Li-IL binderresearch_0309__mat__hkust_1 | Pellet · Target Sample · Guest Loaded | Binder-free Li@MOF pellet in Li||Li@MOF||SUS cell.about 1.0 mm | SI p.S-93 · Supplementary note regarding pure Li@MOF electrolytes · Figure S75 |
| Pure Li@MOF-5 pellet without Li-IL binderresearch_0309__mat__mof_5 | Pellet · Target Sample · Guest Loaded | Binder-free Li@MOF pellet in Li||Li@MOF||SUS cell.about 1.0 mm | SI p.S-93 · Supplementary note regarding pure Li@MOF electrolytes · Figure S75 |
| Pure Li@Zn-MOF-74 pellet without Li-IL binderresearch_0309__mat__zn_mof_74 | Pellet · Target Sample · Guest Loaded | Binder-free Li@MOF pellet in Li||Li@MOF||SUS cell.about 1.0 mm | SI p.S-93 · Supplementary note regarding pure Li@MOF electrolytes · Figure S75 |
| Zn-MOF-74 activated nanoparticlesresearch_0309__mat__zn_mof_74 | Powder · Pristine Control · Pristine Framework | Activated MOF nanoparticle powder stored in an argon-filled glove box unless otherwise specified. | SI pp.S-4-S-7 · Synthesis of MOFs, Li@MOFs, and Li@MOF/Li-IL electrolytes |