From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks
Angel S.M., Barnett N.S., Talin A.A. et al. · Journal of Materials Chemistry C · 2024
Reported here: Cu-MOF-74
This family merges chemical shorthand and formula variants only after verification against source articles. Per-paper composition and phase details remain separate below.
This metal-specific MOF-74/CPO-27 discovery family includes source-verified coordinated-solvent states, whose full formula and activation state remain attached to each record. Reviewed members are classified as 3D frameworks containing 1D channels; pore-direction and structural descriptions remain visible below. Guest-loaded, substituted-linker, mixed-metal and phase-unverified M₂(DOBDC) films remain separate materials.
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3 papers
Angel S.M., Barnett N.S., Talin A.A. et al. · Journal of Materials Chemistry C · 2024
Reported here: Cu-MOF-74
Dong P., Zhang X., Hiscox W. et al. · Advanced Materials · 2023
Reported here: Cu-MOF-74 nanoparticles
Sun L., Hendon C.H., Park S.S. et al. · Chemical Science · 2017
Reported here: Cu2(DOBDC)(DMF)2
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Raw names, formulas and structural assignments remain separate; no consensus value is inferred.
| Paper and reported name | Formula and components | Structure context | Source |
|---|---|---|---|
| Cu-MOF-742024 · From insulator to semiconductor: effect of host-guest interactions on charge transport in M-MOF-74 metal-organic frameworks | Cu2(dobdc) framework, reported as Cu-MOF-74Cu2+ open metal sites in MOF-74 · 2,5-dihydroxyterephthalic acid derived dobdc linker | 3D · PristineIsostructural M-MOF-74 parent framework; open d-shell host. | S-2 · Syntheses |
| Cu-MOF-74 nanoparticles2023 · Toward High-Performance Metal–Organic-Framework-Based Quasi-Solid-State Electrolytes: Tunable Structures and Electrochemical Properties | Cu2(DOBDC)Open Cu2+ sites; redox-active metal centre. · DOBDC linker from H4DOBDC | 3D · PristineMOF-74 framework; phase-pure nanoparticle sample selected at ligand/TEA 1:4. | SI p.S-18 · Supplementary Figures and Tables · Table S2 |
| Cu2(DOBDC)(DMF)22017 · Is iron unique in promoting electrical conductivity in MOFs? | Cu2(C8H2O6)(C3H7NO)2(CH2Cl2)0.35Cu2+ · DOBDC; DMF-coordinated | 3D · Pristinehoneycomb structure with 1D tubular pores | 4451 · Experimental results · Fig. 1 |