Electrical Transport — Is iron unique in promoting electrical conductivity in MOFs?

Measurement evidence

Electrical Transport

Is iron unique in promoting electrical conductivity in MOFs? · Sun L., Hendon C.H., Park S.S. et al. · Chemical Science · 2017 · 4450-4457

40 measurement groups · 40 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Cd(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.4e-13 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Co2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity3.7e-13 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Co2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.5e-13 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Co(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity5.1e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Cu2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.4e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Cu(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity3.2e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Fe2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivityMarked as a best value within this paper1.1e-07 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Fe2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivityMarked as a best value within this paper4.8e-08 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Fe2(DSBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivityMarked as a best value within this paper5.8e-07 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Fe(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivityMarked as a best value within this paper3e-06 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mg2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity2.1e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mg(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity9.9e-15 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mn2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.3e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mn2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity3e-13 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mn2(DSBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.2e-12 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Mn(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity8.2e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Ni2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity2.8e-13 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Ni2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity2.8e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Zn2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity3.3e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

two-contact-probe electrical conductivity from linear regression of J-E curves

pressed pellet of Zn(1,2,3-triazolate)2 · Pellet

Pressed pellets measured at 300 K, under N2 atmosphere, in the dark; Fe-based MOFs measured with Keithley 2450, other metals with Keithley 6517B electrometer.

Temperature
300
Atmosphere
N2; dark
Geometry
in situ pressed pellet between two stainless-steel rods; pellet area 0.0338 cm2; thickness measured by micrometer
Context
pristine MOF pellet
Measurement source
S2-S3 · Room-temperature electrical conductivity measurements · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
electrical conductivity1.2e-14 S/cmSI Table
Exact Reported
S19 · Table S1 · Table S1

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Cd(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.75 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Co2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.86 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Co2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.58 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Co(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.64 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Cu2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.69 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Cu(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.59 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Fe2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energyMarked as a best value within this paper0.39 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Fe2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energyMarked as a best value within this paper0.42 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Fe2(DSBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energyMarked as a best value within this paper0.27 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Fe(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energyMarked as a best value within this paper0.39 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mg2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.64 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mg(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.74 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mn2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.89 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mn2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.55 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mn2(DSBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.81 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Mn(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.59 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Ni2Cl2(BTDD)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.84 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Ni2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.62 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Zn2(DOBDC)(DMF)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.54 eVSI Table
Exact Reported
S41 · Table S2 · Table S2

variable-temperature two-contact I-V curves fitted to Arrhenius law

pressed pellet of Zn(1,2,3-triazolate)2 · Pellet

Pressed pellets measured from 300 to 350 K at 10 K intervals, in vacuum and in the dark; 300 K conductivities normalised to room-temperature values.

Temperature
300-350
Atmosphere
vacuum; dark
Geometry
in situ screw-press pellet in probe station transfer chamber; two-contact geometry
Context
pristine MOF pellet
Measurement source
S3-S4 · Variable-temperature electrical conductivity measurements · Table S2; Fig. S27
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activation energy0.77 eVSI Table
Exact Reported
S41 · Table S2 · Table S2