Porosity — Is iron unique in promoting electrical conductivity in MOFs?

Measurement evidence

Porosity

Is iron unique in promoting electrical conductivity in MOFs? · Sun L., Hendon C.H., Park S.S. et al. · Chemical Science · 2017 · 4450-4457

4 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption isotherm and BET surface-area analysis

pressed pellet of Fe2Cl2(BTDD)(DMF)2 · Pellet

Sample heated to 100 deg C until outgas rate less than 2 mtorr/min; N2 adsorption measured at 77 K.

Temperature
77
Atmosphere
N2 adsorption; He for free-space corrections
Geometry
Micromeritics ASAP 2020 Surface Area and Porosity Analyzer
Context
Fe-based pristine MOF powder
Measurement source
S6 · Gas sorption measurements · Table S3; Fig. S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area365 m2/gSI Table
Exact Reported
S46 · Table S3 · Table S3

N2 adsorption isotherm and BET surface-area analysis

pressed pellet of Fe2(DOBDC)(DMF)2 · Pellet

Sample heated to 100 deg C until outgas rate less than 2 mtorr/min; N2 adsorption measured at 77 K.

Temperature
77
Atmosphere
N2 adsorption; He for free-space corrections
Geometry
Micromeritics ASAP 2020 Surface Area and Porosity Analyzer
Context
Fe-based pristine MOF powder
Measurement source
S6 · Gas sorption measurements · Table S3; Fig. S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area248 m2/gSI Table
Exact Reported
S46 · Table S3 · Table S3

N2 adsorption isotherm and BET surface-area analysis

pressed pellet of Fe2(DSBDC)(DMF)2 · Pellet

Sample heated to 100 deg C until outgas rate less than 2 mtorr/min; N2 adsorption measured at 77 K.

Temperature
77
Atmosphere
N2 adsorption; He for free-space corrections
Geometry
Micromeritics ASAP 2020 Surface Area and Porosity Analyzer
Context
Fe-based pristine MOF powder
Measurement source
S6 · Gas sorption measurements · Table S3; Fig. S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area83 m2/gSI Table
Exact Reported
S46 · Table S3 · Table S3

N2 adsorption isotherm and BET surface-area analysis

pressed pellet of Fe(1,2,3-triazolate)2 · Pellet

Sample heated to 100 deg C until outgas rate less than 2 mtorr/min; N2 adsorption measured at 77 K.

Temperature
77
Atmosphere
N2 adsorption; He for free-space corrections
Geometry
Micromeritics ASAP 2020 Surface Area and Porosity Analyzer
Context
Fe-based pristine MOF powder
Measurement source
S6 · Gas sorption measurements · Table S3; Fig. S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface areaMarked as a best value within this paper443 m2/gSI Table
Exact Reported
S46 · Table S3 · Table S3