Porosity — Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)

Measurement evidence

Porosity

Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O) · Sun L., Hendon C.H., Minier M.A. et al. · Journal of the American Chemical Society · 2015 · 6164-6167

4 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption isotherm and BET surface area

Fe2(DOBDC)(DMF)2 · Pellet

Outgassed at 100 degC; N2 adsorption at 77 K.

Temperature
77
Atmosphere
N2 adsorption
Geometry
Micromeritics ASAP 2020
Context
pristine guest-free framework
Measurement source
6165 · main text · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area241 m2/gText
Exact Reported
6165 · main text · Figure S8

N2 adsorption isotherm and BET surface area

Fe2(DSBDC)(DMF)2 · Pellet

Outgassed at 100 degC until outgas rate <2 mtorr/min; N2 adsorption at 77 K.

Temperature
77
Atmosphere
N2 adsorption; high-purity N2/He
Geometry
Micromeritics ASAP 2020
Context
pristine guest-free framework
Measurement source
S4 · Gas sorption measurements · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area54 m2/gText
Exact Reported
6165 · main text · Figure S8

N2 adsorption isotherm and BET surface area

Mn2(DOBDC)(DMF)2 · Pellet

Outgassed at 100 degC; N2 adsorption at 77 K.

Temperature
77
Atmosphere
N2 adsorption
Geometry
Micromeritics ASAP 2020
Context
pristine guest-free framework
Measurement source
6165 · main text · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface areaMarked as a best value within this paper287 m2/gText
Exact Reported
6165 · main text · Figure S8
N2 uptake at P/P0 approx. 0.9Marked as a best value within this paperca. 76 cm3/g at P/P0 approx. 0.9visual estimate from plotted axisFigure Axis
Approximate
S18 · Figure S8 · Figure S8

N2 adsorption isotherm and BET surface area

Mn2(DSBDC)(DMF)2 · Pellet

Outgassed at 100 degC; N2 adsorption at 77 K.

Temperature
77
Atmosphere
N2 adsorption
Geometry
Micromeritics ASAP 2020
Context
pristine guest-free framework
Measurement source
6165 · main text · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET surface area232 m2/gText
Exact Reported
6165 · main text · Figure S8