Spectroscopy — Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O)

Measurement evidence

Spectroscopy

Million-fold electrical conductivity enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O) · Sun L., Hendon C.H., Minier M.A. et al. · Journal of the American Chemical Society · 2015 · 6164-6167

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

57Fe Mossbauer spectroscopy

Fe2(DOBDC)(DMF)2.x(DMF) · Pellet

Solid sample suspended in Apiezon M grease; measured at 80 K with 57Co source; fit to Lorentzian lines.

Temperature
80
Geometry
MSI spectrometer; nylon sample holder
Context
pristine guest-loaded framework
Measurement source
S7 · Mossbauer spectroscopy measurements · Figure S12
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
57Fe Mossbauer isomer shift1.308 mm/sCaption
Exact Reported
S22 · Figure S12 caption · Figure S12
57Fe Mossbauer line width0.310 mm/sCaption
Exact Reported
S22 · Figure S12 caption · Figure S12
57Fe Mossbauer quadrupole splitting2.739 mm/sCaption
Exact Reported
S22 · Figure S12 caption · Figure S12

57Fe Mossbauer spectroscopy

Fe2(DSBDC)(DMF)2.x(DMF) · Pellet

Solid sample suspended in Apiezon M grease; measured at 80 K with 57Co source; fit to Lorentzian lines.

Temperature
80
Geometry
MSI spectrometer; nylon sample holder
Context
pristine guest-loaded framework
Measurement source
S7 · Mossbauer spectroscopy measurements · Figure S11
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
57Fe Mossbauer isomer shift1.172 mm/sCaption
Exact Reported
S21 · Figure S11 caption · Figure S11
57Fe Mossbauer line width0.440 mm/sCaption
Exact Reported
S21 · Figure S11 caption · Figure S11
57Fe Mossbauer quadrupole splitting3.218 mm/sCaption
Exact Reported
S21 · Figure S11 caption · Figure S11